200 Soal Penyetaraan Jumlah Atom dalam Persamaan Reaksi beserta Jawabannya

Sabtu, 05 April 2025

Berikut ini 200 persamaan reaksi molekuler yang dapat dijadikan latihan untuk penyetaraan reaksi kimia biasa untuk siswa kelas 10 MA/SMA dan juga dapat digunakan untuk latihan penyetaraan reaksi redoks di kelas yang lebih tinggi. Karena tujuannya latihan jangan langsung klik jawabannya, kerjakan mandiri lebih dahulu kemudian cocokan. Untuk melihat hasil setara jumlah unsur/atom antara pada pereaksi dan hasil reaksi sila klik segitiga di kiri setiap nomor persamaan reaksi.

Setarakan persamaan reaksi kimia berikut bila jumlah unsur-unsur yang bersesuaian belum setara:

Persamaan reaksi 3 spesi.

C + O2 → CO
\( aC + bO_2 \rightarrow cCO \)
C: \( a = c \)
O: \( 2b = c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 2C + O2 → 2CO

S + O2 → SO3
\( aS + bO_2 \rightarrow cSO_3 \)
S: \( a = c \)
O: \( 2b = 3c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2b = 6 \Rightarrow b = 3 \)

Setara: 2S + 3O2 → 2SO3

Si + O2 → SiO2
\( aSi + bO_2 \rightarrow cSiO_2 \)
Si: \( a = c \)
O: \( 2b = 2c \)
Misal \( c = 1 \)
\( a = 1 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: Si + O2 → SiO2

PCl3 + Cl2 → PCl5
\( aPCl_3 + bCl_2 \rightarrow cPCl_5 \)
P: \( a = c \)
Cl: \( 3a + 2b = 5c \)
Misal \( c = 1 \)
\( a = 1 \)
\( 3(1) + 2b = 5 \Rightarrow 2b = 2 \Rightarrow b = 1 \)

Setara: PCl3 + Cl2 → PCl5

K + O2 → K2O
\( aK + bO_2 \rightarrow cK_2O \)
K: \( a = 2c \)
O: \( 2b = c \)
Misal \( c = 2 \)
\( a = 4 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 4K + O2 → 2K2O

Mg + O2 → MgO
\( aMg + bO_2 \rightarrow cMgO \)
Mg: \( a = c \)
O: \( 2b = c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 2Mg + O2 → 2MgO

Ca + O2 → CaO
\( aCa + bO_2 \rightarrow cCaO \)
Ca: \( a = c \)
O: \( 2b = c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 2Ca + O2 → 2CaO

Pb + O2 → PbO
\( aPb + bO_2 \rightarrow cPbO \)
Pb: \( a = c \)
O: \( 2b = c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 2Pb + O2 → 2PbO

Cu + O2 → CuO
\( aCu + bO_2 \rightarrow cCuO \)
Cu: \( a = c \)
O: \( 2b = c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 2Cu + O2 → 2CuO

Al + O2 → Al2O3
\( aAl + bO_2 \rightarrow cAl_2O_3 \)
Al: \( a = 2c \)
O: \( 2b = 3c \)
Misal \( c = 2 \)
\( a = 4 \)
\( 2b = 6 \Rightarrow b = 3 \)

Setara: 4Al + 3O2 → 2Al2O3

Fe + O2 → Fe2O3
\( aFe + bO_2 \rightarrow cFe_2O_3 \)
Fe: \( a = 2c \)
O: \( 2b = 3c \)
Misal \( c = 2 \)
\( a = 4 \)
\( 2b = 6 \Rightarrow b = 3 \)

Setara: 4Fe + 3O2 → 2Fe2O3

P + O2 → P2O5
\( aP + bO_2 \rightarrow cP_2O_5 \)
P: \( a = 2c \)
O: \( 2b = 5c \)
Misal \( c = 2 \)
\( a = 4 \)
\( 2b = 10 \Rightarrow b = 5 \)

Setara: 4P + 5O2 → 2P2O5

P4 + O2 → P4O10
\( aP_4 + bO_2 \rightarrow cP_4O_{10} \)
P: \( 4a = 4c \)
O: \( 2b = 10c \)
Misal \( c = 1 \)
\( 4a = 4 \Rightarrow a = 1 \)
\( 2b = 10 \Rightarrow b = 5 \)

Setara: P4 + 5O2 → P4O10

Al + Cl2 → AlCl3
\( aAl + bCl_2 \rightarrow cAlCl_3 \)
Al: \( a = c \)
Cl: \( 2b = 3c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2b = 6 \Rightarrow b = 3 \)

Setara: 2Al + 3Cl2 → 2AlCl3

H2 + O2 → H2O
\( aH_2 + bO_2 \rightarrow cH_2O \)
H: \( 2a = 2c \)
O: \( 2b = c \)
Misal \( c = 2 \)
\( 2a = 4 \Rightarrow a = 2 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 2H2 + O2 → 2H2O

N2 + H2 → NH3
\( aN_2 + bH_2 \rightarrow cNH_3 \)
N: \( 2a = c \)
H: \( 2b = 3c \)
Misal \( c = 2 \)
\( 2a = 2 \Rightarrow a = 1 \)
\( 2b = 6 \Rightarrow b = 3 \)

Setara: N2 + 3H2 → 2NH3

H2 + Cl2 → HCl
\( aH_2 + bCl_2 \rightarrow cHCl \)
H: \( 2a = c \)
Cl: \( 2b = c \)
Misal \( c = 2 \)
\( 2a = 2 \Rightarrow a = 1 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: H2 + Cl2 → 2HCl

Na + Cl2 → NaCl
\( aNa + bCl_2 \rightarrow cNaCl \)
Na: \( a = c \)
Cl: \( 2b = c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 2Na + Cl2 → 2NaCl

CO + O2 → CO2
\( aCO + bO_2 \rightarrow cCO_2 \)
C: \( a = c \)
O: \( a + 2b = 2c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2 + 2b = 4 \Rightarrow 2b = 2 \Rightarrow b = 1 \)

Setara: 2CO + O2 → 2CO2

H2O2 → H2O + O2
\( aH_2O_2 \rightarrow bH_2O + cO_2 \)
H: \( 2a = 2b \)
O: \( 2a = b + 2c \)
Dari H: \( a = b \)
Substitusi ke O: \( 2a = a + 2c \Rightarrow a = 2c \)
Misal \( c = 1 \)
\( a = 2 \)
\( b = 2 \)

Setara: 2H2O2 → 2H2O + O2

SO2 + O2 → SO3
\( aSO_2 + bO_2 \rightarrow cSO_3 \)
S: \( a = c \)
O: \( 2a + 2b = 3c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2(2) + 2b = 3(2) \Rightarrow 4 + 2b = 6 \Rightarrow 2b = 2 \Rightarrow b = 1 \)

Setara: 2SO2 + O2 → 2SO3

N2 + O2 → NO2
\( aN_2 + bO_2 \rightarrow cNO_2 \)
N: \( 2a = c \)
O: \( 2b = 2c \)
Misal \( c = 2 \)
\( 2a = 2 \Rightarrow a = 1 \)
\( 2b = 4 \Rightarrow b = 2 \)

Setara: N2 + 2O2 → 2NO2

NO + O2 → NO2
\( aNO + bO_2 \rightarrow cNO_2 \)
N: \( a = c \)
O: \( a + 2b = 2c \)
Misal \( c = 2 \)
\( a = 2 \)
\( 2 + 2b = 4 \Rightarrow 2b = 2 \Rightarrow b = 1 \)

Setara: 2NO + O2 → 2NO2

H2 + N2 → NH3
\( aH_2 + bN_2 \rightarrow cNH_3 \)
H: \( 2a = 3c \)
N: \( 2b = c \)
Misal \( c = 2 \)
\( 2a = 6 \Rightarrow a = 3 \)
\( 2b = 2 \Rightarrow b = 1 \)

Setara: 3H2 + N2 → 2NH3

Cu + CuSO4 → Cu2SO4
\( aCu + bCuSO_4 \rightarrow cCu_2SO_4 \)
Cu: \( a + b = 2c \)
S: \( b = c \)
O: \( 4b = 4c \)
Dari S: \( b = c \)
Substitusi ke Cu: \( a + c = 2c \Rightarrow a = c \)
Misal \( c = 1 \)
\( a = 1 \)
\( b = 1 \)

Setara: Cu + CuSO4 → Cu2SO4

PbO2 + SO2 → PbSO4
\( aPbO_2 + bSO_2 \rightarrow cPbSO_4 \)
Pb: \( a = c \)
S: \( b = c \)
O: \( 2a + 2b = 4c \)
Misal \( c = 1 \)
\( a = 1 \)
\( b = 1 \)
Cek O: \( 2(1) + 2(1) = 4 \) ✓

Setara: PbO2 + SO2 → PbSO4

Persamaan reaksi 4 spesi.

S + SO2 + H2O → H2SO3
\( aS + bSO_2 + cH_2O \rightarrow dH_2SO_3 \)
S: \( a + b = d \)
O: \( 2b + c = 3d \)
H: \( 2c = 2d \)
Dari H: \( c = d \)
Dari S: \( a + b = d \)
Dari O: \( 2b + d = 3d \Rightarrow 2b = 2d \Rightarrow b = d \)
Misal \( d = 1 \)
\( c = 1 \)
\( b = 1 \)
\( a + 1 = 1 \Rightarrow a = 0 \)
Seharusnya S tidak ada dalam persamaan reaksi.

Setara: SO2 + H2O → H2SO3

CH4 + Cl2 → CH3Cl + HCl
\( aCH_4 + bCl_2 \rightarrow cCH_3Cl + dHCl \)
C: \( a = c \)
H: \( 4a = 3c + d \)
Cl: \( 2b = c + d \)
Misal \( a = 1 \)
\( c = 1 \)
Dari H: \( 4 = 3 + d \Rightarrow d = 1 \)
Dari Cl: \( 2b = 1 + 1 \Rightarrow b = 1 \)

Setara: CH4 + Cl2 → CH3Cl + HCl

FeO + CO → Fe + CO2
\( aFeO + bCO \rightarrow cFe + dCO_2 \)
Fe: \( a = c \)
O: \( a + b = 2d \)
C: \( b = d \)
Misal \( a = 1 \)
\( c = 1 \)
\( b = d \)
Dari O: \( 1 + b = 2b \Rightarrow 1 = b \)
Jadi \( b = 1, d = 1 \)

Setara: FeO + CO → Fe + CO2

Fe3O4 + C → Fe + CO2
\( aFe_3O_4 + bC \rightarrow cFe + dCO_2 \)
Fe: \( 3a = c \)
O: \( 4a = 2d \)
C: \( b = d \)
Misal \( a = 1 \)
\( c = 3 \)
\( 4 = 2d \Rightarrow d = 2 \)
\( b = 2 \)

Setara: Fe3O4 + 4C → 3Fe + 4CO2

Fe + H2SO4 → FeSO4 + H2
\( aFe + bH_2SO_4 \rightarrow cFeSO_4 + dH_2 \)
Fe: \( a = c \)
H: \( 2b = 2d \)
S: \( b = c \)
O: \( 4b = 4c \)
Dari Fe dan S: \( a = b = c \)
Dari H: \( b = d \)
Misal \( a = 1 \)
\( b = 1, c = 1, d = 1 \)

Setara: Fe + H2SO4 → FeSO4 + H2

FeS + H2SO4 → FeSO4 + H2S
\( aFeS + bH_2SO_4 \rightarrow cFeSO_4 + dH_2S \)
Fe: \( a = c \)
S: \( a + b = c + d \)
H: \( 2b = 2d \)
O: \( 4b = 4c \)
Dari H: \( b = d \)
Dari O: \( b = c \)
Jadi \( a = b = c = d \)
Misal \( a = 1 \)
\( b = 1, c = 1, d = 1 \)

Setara: FeS + H2SO4 → FeSO4 + H2S

ZnS + H2SO4 → ZnSO4 + H2S
\( aZnS + bH_2SO_4 \rightarrow cZnSO_4 + dH_2S \)
Zn: \( a = c \)
S: \( a + b = c + d \)
H: \( 2b = 2d \)
O: \( 4b = 4c \)
Dari H: \( b = d \)
Dari O: \( b = c \)
Jadi \( a = b = c = d \)
Misal \( a = 1 \)
\( b = 1, c = 1, d = 1 \)

Setara: ZnS + H2SO4 → ZnSO4 + H2S

PbO + HNO3 → Pb(NO3)2 + H2O
\( aPbO + bHNO_3 \rightarrow cPb(NO_3)_2 + dH_2O \)
Pb: \( a = c \)
H: \( b = 2d \)
N: \( b = 2c \)
O: \( a + 3b = 6c + d \)
Dari N: \( b = 2c \)
Dari H: \( 2c = 2d \Rightarrow c = d \)
Misal \( c = 1 \)
\( a = 1, d = 1, b = 2 \)

Setara: PbO + 2HNO3 → Pb(NO3)2 + H2O

Mg + HNO3 → Mg(NO3)2 + H2
\( aMg + bHNO_3 \rightarrow cMg(NO_3)_2 + dH_2 \)
Mg: \( a = c \)
H: \( b = 2d \)
N: \( b = 2c \)
O: \( 3b = 6c \)
Dari N: \( b = 2c \)
Dari H: \( 2c = 2d \Rightarrow c = d \)
Misal \( c = 1 \)
\( a = 1, d = 1, b = 2 \)

Setara: Mg + 2HNO3 → Mg(NO3)2 + H2

Zn + HNO3 → Zn(NO3)2 + H2
\( aZn + bHNO_3 \rightarrow cZn(NO_3)_2 + dH_2 \)
Zn: \( a = c \)
H: \( b = 2d \)
N: \( b = 2c \)
O: \( 3b = 6c \)
Dari N: \( b = 2c \)
Dari H: \( 2c = 2d \Rightarrow c = d \)
Misal \( c = 1 \)
\( a = 1, d = 1, b = 2 \)

Setara: Zn + 2HNO3 → Zn(NO3)2 + H2

CH2O + O2 → CO2 + H2O
\( aCH_2O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( a = c \)
H: \( 2a = 2d \)
O: \( a + 2b = 2c + d \)
Dari H: \( a = d \)
Dari C: \( a = c \)
Jadi \( a = c = d \)
Misal \( a = 1 \)
\( c = 1, d = 1 \)
Dari O: \( 1 + 2b = 2 + 1 \Rightarrow 2b = 2 \Rightarrow b = 1 \)

Setara: CH2O + O2 → CO2 + H2O

H2S + SO2 → S + H2O
\( aH_2S + bSO_2 \rightarrow cS + dH_2O \)
H: \( 2a = 2d \)
S: \( a + b = c \)
O: \( 2b = d \)
Dari H: \( a = d \)
Dari O: \( 2b = a \Rightarrow a = 2b \)
Dari S: \( 2b + b = c \Rightarrow 3b = c \)
Misal \( b = 1 \)
\( a = 2, c = 3, d = 2 \)

Setara: 2H2S + SO2 → 3S + 2H2O

PbO2 + H2 → Pb + H2O
\( aPbO_2 + bH_2 \rightarrow cPb + dH_2O \)
Pb: \( a = c \)
H: \( 2b = 2d \)
O: \( 2a = d \)
Dari H: \( b = d \)
Dari O: \( 2a = b \)
Misal \( a = 1 \)
\( c = 1, b = 2, d = 2 \)

Setara: PbO2 + 2H2 → Pb + 2H2O

C2H4 + O2 → CO2 + H2O
\( aC_2H_4 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 2a = c \)
H: \( 4a = 2d \)
O: \( 2b = 2c + d \)
Dari H: \( 2a = d \)
Dari C: \( c = 2a \)
Misal \( a = 1 \)
\( c = 2, d = 2 \)
Dari O: \( 2b = 2(2) + 2 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: C2H4 + 3O2 → 2CO2 + 2H2O

C2H5OH + O2 → CO2 + H2O
\( aC_2H_5OH + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 2a = c \)
H: \( 6a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 2 \)
\( 6 = 2d \Rightarrow d = 3 \)
Dari O: \( 1 + 2b = 2(2) + 3 \Rightarrow 1 + 2b = 7 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: C2H5OH + 3O2 → 2CO2 + 3H2O

CH3OH + O2 → CO2 + H2O
\( aCH_3OH + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( a = c \)
H: \( 4a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 2 \)
\( 4(2) = 2d \Rightarrow 8 = 2d \Rightarrow d = 4 \)
Dari O: \( 2 + 2b = 2(2) + 4 \Rightarrow 2 + 2b = 8 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: 2CH3OH + 3O2 → 2CO2 + 4H2O

CS2 + O2 → CO2 + SO2
\( aCS_2 + bO_2 \rightarrow cCO_2 + dSO_2 \)
C: \( a = c \)
S: \( 2a = d \)
O: \( 2b = 2c + 2d \)
Misal \( a = 1 \)
\( c = 1 \)
\( d = 2 \)
Dari O: \( 2b = 2(1) + 2(2) \Rightarrow 2b = 2 + 4 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: CS2 + 3O2 → CO2 + 2SO2

H2S + O2 → SO2 + H2O
\( aH_2S + bO_2 \rightarrow cSO_2 + dH_2O \)
H: \( 2a = 2d \)
S: \( a = c \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 2 \)
\( 2(2) = 2d \Rightarrow 4 = 2d \Rightarrow d = 2 \)
Dari O: \( 2b = 2(2) + 2 \Rightarrow 2b = 4 + 2 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: 2H2S + 3O2 → 2SO2 + 2H2O

2H2 + SO2 → S + 2H2O
\( aH_2 + bSO_2 \rightarrow cS + dH_2O \)
H: \( 2a = 2d \)
S: \( b = c \)
O: \( 2b = d \)
Dari H: \( a = d \)
Dari O: \( 2b = a \)
Misal \( b = 1 \)
\( c = 1 \)
\( a = 2(1) = 2 \)
\( d = 2 \)

Setara: 2H2 + SO2 → S + 2H2O

Cu2S + O2 → Cu + SO2
\( aCu_2S + bO_2 \rightarrow cCu + dSO_2 \)
Cu: \( 2a = c \)
S: \( a = d \)
O: \( 2b = 2d \)
Misal \( a = 1 \)
\( d = 1 \)
\( c = 2 \)
Dari O: \( 2b = 2(1) \Rightarrow 2b = 2 \Rightarrow b = 1 \)

Setara: Cu2S + O2 → 2Cu + SO2

PbS + PbO → Pb + SO2
\( aPbS + bPbO \rightarrow cPb + dSO_2 \)
Pb: \( a + b = c \)
S: \( a = d \)
O: \( b = 2d \)
Misal \( a = 1 \)
\( d = 1 \)
\( b = 2(1) = 2 \)
\( c = 1 + 2 = 3 \)

Setara: PbS + 2PbO → 3Pb + SO2

PbO + C → Pb + CO2
\( aPbO + bC \rightarrow cPb + dCO_2 \)
Pb: \( a = c \)
O: \( a = 2d \)
C: \( b = d \)
Misal \( d = 1 \)
\( a = 2 \)
\( c = 2 \)
\( b = 1 \)

Setara: 2PbO + C → 2Pb + CO2

NH3 + O2 → NO + H2O
\( aNH_3 + bO_2 \rightarrow cNO + dH_2O \)
N: \( a = c \)
H: \( 3a = 2d \)
O: \( 2b = c + d \)
Misal \( a = 4 \)
\( c = 4 \)
\( 3(4) = 2d \Rightarrow 12 = 2d \Rightarrow d = 6 \)
Dari O: \( 2b = 4 + 6 \Rightarrow 2b = 10 \Rightarrow b = 5 \)

Setara: 4NH3 + 5O2 → 4NO + 6H2O

NH3 + O2 → N2 + H2O
\( aNH_3 + bO_2 \rightarrow cN_2 + dH_2O \)
N: \( a = 2c \)
H: \( 3a = 2d \)
O: \( 2b = d \)
Misal \( c = 1 \)
\( a = 2 \)
\( 3(2) = 2d \Rightarrow 6 = 2d \Rightarrow d = 3 \)
\( 2b = 3 \Rightarrow b = 1.5 \)
Kalikan 2: \( a = 4, b = 3, c = 2, d = 6 \)

Setara: 4NH3 + 3O2 → 2N2 + 6H2O

C3H8 + O2 → CO2 + H2O
\( aC_3H_8 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 3a = c \)
H: \( 8a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 3 \)
\( 8 = 2d \Rightarrow d = 4 \)
\( 2b = 2(3) + 4 \Rightarrow 2b = 6 + 4 \Rightarrow 2b = 10 \Rightarrow b = 5 \)

Setara: C3H8 + 5O2 → 3CO2 + 4H2O

CH4 + O2 → CO2 + H2O
\( aCH_4 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( a = c \)
H: \( 4a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 1 \)
\( 4 = 2d \Rightarrow d = 2 \)
\( 2b = 2(1) + 2 \Rightarrow 2b = 2 + 2 \Rightarrow 2b = 4 \Rightarrow b = 2 \)

Setara: CH4 + 2O2 → CO2 + 2H2O

C4H10 + O2 → CO2 + H2O
\( aC_4H_{10} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 4a = c \)
H: \( 10a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 8 \)
\( 10(2) = 2d \Rightarrow 20 = 2d \Rightarrow d = 10 \)
\( 2b = 2(8) + 10 \Rightarrow 2b = 16 + 10 \Rightarrow 2b = 26 \Rightarrow b = 13 \)

Setara: 2C4H10 + 13O2 → 8CO2 + 10H2O

C5H12 + O2 → CO2 + H2O
\( aC_5H_{12} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 5a = c \)
H: \( 12a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 5 \)
\( 12 = 2d \Rightarrow d = 6 \)
\( 2b = 2(5) + 6 \Rightarrow 2b = 10 + 6 \Rightarrow 2b = 16 \Rightarrow b = 8 \)

Setara: C5H12 + 8O2 → 5CO2 + 6H2O

C7H16 + O2 → CO2 + H2O
\( aC_7H_{16} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 16a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 7 \)
\( 16 = 2d \Rightarrow d = 8 \)
\( 2b = 2(7) + 8 \Rightarrow 2b = 14 + 8 \Rightarrow 2b = 22 \Rightarrow b = 11 \)

Setara: C7H16 + 11O2 → 7CO2 + 8H2O

C8H18 + O2 → CO2 + H2O
\( aC_8H_{18} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 8a = c \)
H: \( 18a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 16 \)
\( 18(2) = 2d \Rightarrow 36 = 2d \Rightarrow d = 18 \)
\( 2b = 2(16) + 18 \Rightarrow 2b = 32 + 18 \Rightarrow 2b = 50 \Rightarrow b = 25 \)

Setara: 2C8H18 + 25O2 → 16CO2 + 18H2O

C9H20 + O2 → CO2 + H2O
\( aC_9H_{20} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 9a = c \)
H: \( 20a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 9 \)
\( 20 = 2d \Rightarrow d = 10 \)
\( 2b = 2(9) + 10 \Rightarrow 2b = 18 + 10 \Rightarrow 2b = 28 \Rightarrow b = 14 \)

Setara: C9H20 + 14O2 → 9CO2 + 10H2O

C10H22 + O2 → CO2 + H2O
\( aC_{10}H_{22} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 10a = c \)
H: \( 22a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 20 \)
\( 22(2) = 2d \Rightarrow 44 = 2d \Rightarrow d = 22 \)
\( 2b = 2(20) + 22 \Rightarrow 2b = 40 + 22 \Rightarrow 2b = 62 \Rightarrow b = 31 \)

Setara: 2C10H22 + 31O2 → 20CO2 + 22H2O

C4H8 + O2 → CO2 + H2O
\( aC_4H_8 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 4a = c \)
H: \( 8a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 4 \)
\( 8 = 2d \Rightarrow d = 4 \)
\( 2b = 2(4) + 4 \Rightarrow 2b = 8 + 4 \Rightarrow 2b = 12 \Rightarrow b = 6 \)

Setara: C4H8 + 6O2 → 4CO2 + 4H2O

C6H12 + O2 → CO2 + H2O
\( aC_6H_{12} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 6a = c \)
H: \( 12a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 6 \)
\( 12 = 2d \Rightarrow d = 6 \)
\( 2b = 2(6) + 6 \Rightarrow 2b = 12 + 6 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: C6H12 + 9O2 → 6CO2 + 6H2O

C7H14 + O2 → CO2 + H2O
\( aC_7H_{14} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 14a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 14 \)
\( 14(2) = 2d \Rightarrow 28 = 2d \Rightarrow d = 14 \)
\( 2b = 2(14) + 14 \Rightarrow 2b = 28 + 14 \Rightarrow 2b = 42 \Rightarrow b = 21 \)

Setara: 2C7H14 + 21O2 → 14CO2 + 14H2O

C8H16 + O2 → CO2 + H2O
\( aC_8H_{16} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 8a = c \)
H: \( 16a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 8 \)
\( 16 = 2d \Rightarrow d = 8 \)
\( 2b = 2(8) + 8 \Rightarrow 2b = 16 + 8 \Rightarrow 2b = 24 \Rightarrow b = 12 \)

Setara: C8H16 + 12O2 → 8CO2 + 8H2O

C9H18 + O2 → CO2 + H2O
\( aC_9H_{18} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 9a = c \)
H: \( 18a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 18 \)
\( 18(2) = 2d \Rightarrow 36 = 2d \Rightarrow d = 18 \)
\( 2b = 2(18) + 18 \Rightarrow 2b = 36 + 18 \Rightarrow 2b = 54 \Rightarrow b = 27 \)

Setara: 2C9H18 + 27O2 → 18CO2 + 18H2O

C10H20 + O2 → CO2 + H2O
\( aC_{10}H_{20} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 10a = c \)
H: \( 20a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 10 \)
\( 20 = 2d \Rightarrow d = 10 \)
\( 2b = 2(10) + 10 \Rightarrow 2b = 20 + 10 \Rightarrow 2b = 30 \Rightarrow b = 15 \)

Setara: C10H20 + 15O2 → 10CO2 + 10H2O

C11H22 + O2 → CO2 + H2O
\( aC_{11}H_{22} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 11a = c \)
H: \( 22a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 22 \)
\( 22(2) = 2d \Rightarrow 44 = 2d \Rightarrow d = 22 \)
\( 2b = 2(22) + 22 \Rightarrow 2b = 44 + 22 \Rightarrow 2b = 66 \Rightarrow b = 33 \)

Setara: 2C11H22 + 33O2 → 22CO2 + 22H2O

C12H24 + O2 → CO2 + H2O
\( aC_{12}H_{24} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 12a = c \)
H: \( 24a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 12 \)
\( 24 = 2d \Rightarrow d = 12 \)
\( 2b = 2(12) + 12 \Rightarrow 2b = 24 + 12 \Rightarrow 2b = 36 \Rightarrow b = 18 \)

Setara: C12H24 + 18O2 → 12CO2 + 12H2O

C13H26 + O2 → CO2 + H2O
\( aC_{13}H_{26} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 13a = c \)
H: \( 26a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 26 \)
\( 26(2) = 2d \Rightarrow 52 = 2d \Rightarrow d = 26 \)
\( 2b = 2(26) + 26 \Rightarrow 2b = 52 + 26 \Rightarrow 2b = 78 \Rightarrow b = 39 \)

Setara: 2C13H26 + 39O2 → 26CO2 + 26H2O

C14H28 + O2 → CO2 + H2O
\( aC_{14}H_{28} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 14a = c \)
H: \( 28a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 14 \)
\( 28 = 2d \Rightarrow d = 14 \)
\( 2b = 2(14) + 14 \Rightarrow 2b = 28 + 14 \Rightarrow 2b = 42 \Rightarrow b = 21 \)

Setara: C14H28 + 21O2 → 14CO2 + 14H2O

C15H30 + O2 → CO2 + H2O
\( aC_{15}H_{30} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 15a = c \)
H: \( 30a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 30 \)
\( 30(2) = 2d \Rightarrow 60 = 2d \Rightarrow d = 30 \)
\( 2b = 2(30) + 30 \Rightarrow 2b = 60 + 30 \Rightarrow 2b = 90 \Rightarrow b = 45 \)

Setara: 2C15H30 + 45O2 → 30CO2 + 30H2O

CH3COOH + O2 → CO2 + H2O
\( aCH_3COOH + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 2a = c \)
H: \( 4a = 2d \)
O: \( 2a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 4 \)
\( 4(2) = 2d \Rightarrow 8 = 2d \Rightarrow d = 4 \)
\( 2(2) + 2b = 2(4) + 4 \Rightarrow 4 + 2b = 8 + 4 \Rightarrow 4 + 2b = 12 \Rightarrow 2b = 8 \Rightarrow b = 4 \)

Setara: 2CH3COOH + 4O2 → 4CO2 + 4H2O

C4H9OH + O2 → CO2 + H2O
\( aC_4H_9OH + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 4a = c \)
H: \( 10a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 4 \)
\( 10 = 2d \Rightarrow d = 5 \)
\( 1 + 2b = 2(4) + 5 \Rightarrow 1 + 2b = 8 + 5 \Rightarrow 1 + 2b = 13 \Rightarrow 2b = 12 \Rightarrow b = 6 \)

Setara: C4H9OH + 6O2 → 4CO2 + 5H2O

C5H11OH + O2 → CO2 + H2O
\( aC_5H_{11}OH + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 5a = c \)
H: \( 12a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 10 \)
\( 12(2) = 2d \Rightarrow 24 = 2d \Rightarrow d = 12 \)
\( 2 + 2b = 2(10) + 12 \Rightarrow 2 + 2b = 20 + 12 \Rightarrow 2 + 2b = 32 \Rightarrow 2b = 30 \Rightarrow b = 15 \)

Setara: 2C5H11OH + 15O2 → 10CO2 + 12H2O

C7H15OH + O2 → CO2 + H2O
\( aC_7H_{15}OH + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 16a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 14 \)
\( 16(2) = 2d \Rightarrow 32 = 2d \Rightarrow d = 16 \)
\( 2 + 2b = 2(14) + 16 \Rightarrow 2 + 2b = 28 + 16 \Rightarrow 2 + 2b = 44 \Rightarrow 2b = 42 \Rightarrow b = 21 \)

Setara: 2C7H15OH + 21O2 → 14CO2 + 16H2O

C8H17OH + O2 → CO2 + H2O
\( aC_8H_{17}OH + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 8a = c \)
H: \( 18a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 8 \)
\( 18 = 2d \Rightarrow d = 9 \)
\( 1 + 2b = 2(8) + 9 \Rightarrow 1 + 2b = 16 + 9 \Rightarrow 1 + 2b = 25 \Rightarrow 2b = 24 \Rightarrow b = 12 \)

Setara: C8H17OH + 12O2 → 8CO2 + 9H2O

C4H10O + O2 → CO2 + H2O
\( aC_4H_{10}O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 4a = c \)
H: \( 10a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 4 \)
\( 10 = 2d \Rightarrow d = 5 \)
\( 1 + 2b = 2(4) + 5 \Rightarrow 1 + 2b = 8 + 5 \Rightarrow 1 + 2b = 13 \Rightarrow 2b = 12 \Rightarrow b = 6 \)

Setara: C4H10O + 6O2 → 4CO2 + 5H2O

C5H10O + O2 → CO2 + H2O
\( aC_5H_{10}O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 5a = c \)
H: \( 10a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 5 \)
\( 10 = 2d \Rightarrow d = 5 \)
\( 1 + 2b = 2(5) + 5 \Rightarrow 1 + 2b = 10 + 5 \Rightarrow 1 + 2b = 15 \Rightarrow 2b = 14 \Rightarrow b = 7 \)

Setara: C5H10O + 7O2 → 5CO2 + 5H2O

CH3CH2CH2OH + O2 → CO2 + H2O
\( aC_3H_8O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 3a = c \)
H: \( 8a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 6 \)
\( 8(2) = 2d \Rightarrow 16 = 2d \Rightarrow d = 8 \)
\( 2 + 2b = 2(6) + 8 \Rightarrow 2 + 2b = 12 + 8 \Rightarrow 2 + 2b = 20 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: 2CH3CH2CH2OH + 9O2 → 6CO2 + 8H2O

CH3CH2CH2CH2OH + O2 → CO2 + H2O
\( aC_4H_{10}O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 4a = c \)
H: \( 10a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 4 \)
\( 10 = 2d \Rightarrow d = 5 \)
\( 1 + 2b = 2(4) + 5 \Rightarrow 1 + 2b = 8 + 5 \Rightarrow 1 + 2b = 13 \Rightarrow 2b = 12 \Rightarrow b = 6 \)

Setara: CH3CH2CH2CH2OH + 6O2 → 4CO2 + 5H2O

CH3CH2COOH + O2 → CO2 + H2O
\( aC_3H_6O_2 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 3a = c \)
H: \( 6a = 2d \)
O: \( 2a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 6 \)
\( 6(2) = 2d \Rightarrow 12 = 2d \Rightarrow d = 6 \)
\( 2(2) + 2b = 2(6) + 6 \Rightarrow 4 + 2b = 12 + 6 \Rightarrow 4 + 2b = 18 \Rightarrow 2b = 14 \Rightarrow b = 7 \)

Setara: 2CH3CH2COOH + 7O2 → 6CO2 + 6H2O

CH3CH2CH2COOH + O2 → CO2 + H2O
\( aC_4H_8O_2 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 4a = c \)
H: \( 8a = 2d \)
O: \( 2a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 4 \)
\( 8 = 2d \Rightarrow d = 4 \)
\( 2(1) + 2b = 2(4) + 4 \Rightarrow 2 + 2b = 8 + 4 \Rightarrow 2 + 2b = 12 \Rightarrow 2b = 10 \Rightarrow b = 5 \)

Setara: CH3CH2CH2COOH + 5O2 → 4CO2 + 4H2O

C7H15COOH + O2 → CO2 + H2O
\( aC_8H_{16}O_2 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 8a = c \)
H: \( 16a = 2d \)
O: \( 2a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 8 \)
\( 16 = 2d \Rightarrow d = 8 \)
\( 2(1) + 2b = 2(8) + 8 \Rightarrow 2 + 2b = 16 + 8 \Rightarrow 2 + 2b = 24 \Rightarrow 2b = 22 \Rightarrow b = 11 \)

Setara: C7H15COOH + 11O2 → 8CO2 + 8H2O

CH3COCH3 + O2 → CO2 + H2O
\( aC_3H_6O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 3a = c \)
H: \( 6a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 3 \)
\( 6 = 2d \Rightarrow d = 3 \)
\( 1 + 2b = 2(3) + 3 \Rightarrow 1 + 2b = 6 + 3 \Rightarrow 1 + 2b = 9 \Rightarrow 2b = 8 \Rightarrow b = 4 \)

Setara: CH3COCH3 + 4O2 → 3CO2 + 3H2O

C6H12O2 + O2 → CO2 + H2O
\( aC_6H_{12}O_2 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 6a = c \)
H: \( 12a = 2d \)
O: \( 2a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 6 \)
\( 12 = 2d \Rightarrow d = 6 \)
\( 2(1) + 2b = 2(6) + 6 \Rightarrow 2 + 2b = 12 + 6 \Rightarrow 2 + 2b = 18 \Rightarrow 2b = 16 \Rightarrow b = 8 \)

Setara: C6H12O2 + 8O2 → 6CO2 + 6H2O

Fe2O3 + CO → Fe + CO2
\( aFe_2O_3 + bCO \rightarrow cFe + dCO_2 \)
Fe: \( 2a = c \)
O: \( 3a + b = 2d \)
C: \( b = d \)
Misal \( a = 1 \)
\( c = 2 \)
\( b = d \)
Dari O: \( 3 + b = 2b \Rightarrow 3 = b \)
Jadi \( b = 3, d = 3 \)

Setara: Fe2O3 + 3CO → 2Fe + 3CO2

Fe2O3 + H2 → Fe + H2O
\( aFe_2O_3 + bH_2 \rightarrow cFe + dH_2O \)
Fe: \( 2a = c \)
O: \( 3a = d \)
H: \( 2b = 2d \)
Misal \( a = 1 \)
\( c = 2 \)
\( d = 3 \)
\( 2b = 2(3) \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: Fe2O3 + 3H2 → 2Fe + 3H2O

Fe3O4 + CO → Fe + CO2
\( aFe_3O_4 + bCO \rightarrow cFe + dCO_2 \)
Fe: \( 3a = c \)
O: \( 4a + b = 2d \)
C: \( b = d \)
Misal \( a = 1 \)
\( c = 3 \)
\( b = d \)
Dari O: \( 4 + b = 2b \Rightarrow 4 = b \)
Jadi \( b = 4, d = 4 \)

Setara: Fe3O4 + 4CO → 3Fe + 4CO2

Fe3O4 + H2 → Fe + H2O
\( aFe_3O_4 + bH_2 \rightarrow cFe + dH_2O \)
Fe: \( 3a = c \)
O: \( 4a = d \)
H: \( 2b = 2d \)
Misal \( a = 1 \)
\( c = 3 \)
\( d = 4 \)
\( 2b = 2(4) \Rightarrow 2b = 8 \Rightarrow b = 4 \)

Setara: Fe3O4 + 4H2 → 3Fe + 4H2O

Pb3O4 + H2 → Pb + H2O
\( aPb_3O_4 + bH_2 \rightarrow cPb + dH_2O \)
Pb: \( 3a = c \)
O: \( 4a = d \)
H: \( 2b = 2d \)
Misal \( a = 1 \)
\( c = 3 \)
\( d = 4 \)
\( 2b = 2(4) \Rightarrow 2b = 8 \Rightarrow b = 4 \)

Setara: Pb3O4 + 4H2 → 3Pb + 4H2O

Fe2O3 + C → Fe + CO
\( aFe_2O_3 + bC \rightarrow cFe + dCO \)
Fe: \( 2a = c \)
O: \( 3a = d \)
C: \( b = d \)
Misal \( a = 1 \)
\( c = 2 \)
\( d = 3 \)
\( b = 3 \)

Setara: Fe2O3 + 3C → 2Fe + 3CO

Fe2O3 + Al → Al2O3 + Fe
\( aFe_2O_3 + bAl \rightarrow cAl_2O_3 + dFe \)
Fe: \( 2a = d \)
O: \( 3a = 3c \)
Al: \( b = 2c \)
Dari O: \( a = c \)
Misal \( a = 1 \)
\( c = 1 \)
\( d = 2 \)
\( b = 2 \)

Setara: Fe2O3 + 2Al → Al2O3 + 2Fe

Al + H2SO4 → Al2(SO4)3 + H2
\( aAl + bH_2SO_4 \rightarrow cAl_2(SO_4)_3 + dH_2 \)
Al: \( a = 2c \)
H: \( 2b = 2d \)
S: \( b = 3c \)
O: \( 4b = 12c \)
Misal \( c = 1 \)
\( a = 2 \)
\( b = 3 \)
Dari H: \( 2(3) = 2d \Rightarrow 6 = 2d \Rightarrow d = 3 \)

Setara: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2

Mg + H2SO4 → MgSO4 + H2
\( aMg + bH_2SO_4 \rightarrow cMgSO_4 + dH_2 \)
Mg: \( a = c \)
H: \( 2b = 2d \)
S: \( b = c \)
O: \( 4b = 4c \)
Misal \( a = 1 \)
\( c = 1, b = 1, d = 1 \)

Setara: Mg + H2SO4 → MgSO4 + H2

Fe2(SO4)3 + H2 → Fe + H2SO4
\( aFe_2(SO_4)_3 + bH_2 \rightarrow cFe + dH_2SO_4 \)
Fe: \( 2a = c \)
S: \( 3a = d \)
O: \( 12a = 4d \)
H: \( 2b = 2d \)
Misal \( a = 1 \)
\( c = 2, d = 3 \)
\( 2b = 2(3) \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: Fe2(SO4)3 + 3H2 → 2Fe + 3H2SO4

C2H6 + O2 → CO2 + H2O
\( aC_2H_6 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 2a = c \)
H: \( 6a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 4 \)
\( 6(2) = 2d \Rightarrow 12 = 2d \Rightarrow d = 6 \)
\( 2b = 2(4) + 6 \Rightarrow 2b = 8 + 6 \Rightarrow 2b = 14 \Rightarrow b = 7 \)

Setara: 2C2H6 + 7O2 → 4CO2 + 6H2O

Fe2O3 + SO2 + O2 → Fe2(SO4)3
\( aFe_2O_3 + bSO_2 + cO_2 \rightarrow dFe_2(SO_4)_3 \)
Fe: \( 2a = 2d \) → \( a = d \)      (1)
S: \( b = 3d \)      (2)
O: \( 3a + 2b + 2c = 12d \)      (3)
Dari (1): \( a = d \)
Dari (2): \( b = 3d \)
Substitusi ke (3):
\( 3d + 2(3d) + 2c = 12d \)
\( 3d + 6d + 2c = 12d \)
\( 9d + 2c = 12d \)
\( 2c = 3d \)
\( c = \dfrac{3}{2}d \)      (4)
Pilih \( d = 2 \) (untuk menghilangkan pecahan):
\( a = 2 \)
\( b = 3 \times 2 = 6 \)
\( c = \dfrac{3}{2} \times 2 = 3 \)
Mengecek keseimbangan semua atom:
Fe: Reaktan = \( 2a = 4 \), Produk = \( 2d = 4 \) ✓
S: Reaktan = \( b = 6 \), Produk = \( 3d = 6 \) ✓
O: Reaktan = \( 3a + 2b + 2c = 6 + 12 + 6 = 24 \), Produk = \( 12d = 24 \) ✓

Persamaan reaksi setara:
\( 2Fe_2O_3 + 6SO_2 + 3O_2 \rightarrow 2Fe_2(SO_4)_3 \)

C6H12O6 + O2 → CO2 + H2O
\( aC_6H_{12}O_6 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 6a = c \)
H: \( 12a = 2d \)
O: \( 6a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 6 \)
\( 12 = 2d \Rightarrow d = 6 \)
\( 6 + 2b = 2(6) + 6 \Rightarrow 6 + 2b = 12 + 6 \Rightarrow 6 + 2b = 18 \Rightarrow 2b = 12 \Rightarrow b = 6 \)

Setara: C6H12O6 + 6O2 → 6CO2 + 6H2O

C10H8 + O2 → CO2 + H2O
\( aC_{10}H_8 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 10a = c \)
H: \( 8a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 10 \)
\( 8 = 2d \Rightarrow d = 4 \)
\( 2b = 2(10) + 4 \Rightarrow 2b = 20 + 4 \Rightarrow 2b = 24 \Rightarrow b = 12 \)

Setara: C10H8 + 12O2 → 10CO2 + 4H2O

C6H6 + O2 → CO2 + H2O
\( aC_6H_6 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 6a = c \)
H: \( 6a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 12 \)
\( 6(2) = 2d \Rightarrow 12 = 2d \Rightarrow d = 6 \)
\( 2b = 2(12) + 6 \Rightarrow 2b = 24 + 6 \Rightarrow 2b = 30 \Rightarrow b = 15 \)

Setara: 2C6H6 + 15O2 → 12CO2 + 6H2O

C7H8 + O2 → CO2 + H2O
\( aC_7H_8 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 8a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 7 \)
\( 8 = 2d \Rightarrow d = 4 \)
\( 2b = 2(7) + 4 \Rightarrow 2b = 14 + 4 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: C7H8 + 9O2 → 7CO2 + 4H2O

C8H10 + O2 → CO2 + H2O
\( aC_8H_{10} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 8a = c \)
H: \( 10a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 16 \)
\( 10(2) = 2d \Rightarrow 20 = 2d \Rightarrow d = 10 \)
\( 2b = 2(16) + 10 \Rightarrow 2b = 32 + 10 \Rightarrow 2b = 42 \Rightarrow b = 21 \)

Setara: 2C8H10 + 21O2 → 16CO2 + 10H2O

C6H5CH3 + O2 → CO2 + H2O
\( aC_7H_8 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 8a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 7 \)
\( 8 = 2d \Rightarrow d = 4 \)
\( 2b = 2(7) + 4 \Rightarrow 2b = 14 + 4 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: C6H5CH3 + 9O2 → 7CO2 + 4H2O

C6H5OH + O2 → CO2 + H2O
\( aC_6H_6O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 6a = c \)
H: \( 6a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 6 \)
\( 6 = 2d \Rightarrow d = 3 \)
\( 1 + 2b = 2(6) + 3 \Rightarrow 1 + 2b = 12 + 3 \Rightarrow 1 + 2b = 15 \Rightarrow 2b = 14 \Rightarrow b = 7 \)

Setara: C6H5OH + 7O2 → 6CO2 + 3H2O

C6H5COOH + O2 → CO2 + H2O
\( aC_7H_6O_2 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 6a = 2d \)
O: \( 2a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 14 \)
\( 6(2) = 2d \Rightarrow 12 = 2d \Rightarrow d = 6 \)
\( 2(2) + 2b = 2(14) + 6 \Rightarrow 4 + 2b = 28 + 6 \Rightarrow 4 + 2b = 34 \Rightarrow 2b = 30 \Rightarrow b = 15 \)

Setara: 2C6H5COOH + 15O2 → 14CO2 + 6H2O

C6H5CH2OH + O2 → CO2 + H2O
\( aC_7H_8O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 8a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 14 \)
\( 8(2) = 2d \Rightarrow 16 = 2d \Rightarrow d = 8 \)
\( 2 + 2b = 2(14) + 8 \Rightarrow 2 + 2b = 28 + 8 \Rightarrow 2 + 2b = 36 \Rightarrow 2b = 34 \Rightarrow b = 17 \)

Setara: 2C6H5CH2OH + 17O2 → 14CO2 + 8H2O

C6H5COCH3 + O2 → CO2 + H2O
\( aC_8H_8O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 8a = c \)
H: \( 8a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 16 \)
\( 8(2) = 2d \Rightarrow 16 = 2d \Rightarrow d = 8 \)
\( 2 + 2b = 2(16) + 8 \Rightarrow 2 + 2b = 32 + 8 \Rightarrow 2 + 2b = 40 \Rightarrow 2b = 38 \Rightarrow b = 19 \)

Setara: 2C6H5COCH3 + 19O2 → 16CO2 + 8H2O

CH3CHO + O2 → CO2 + H2O
\( aC_2H_4O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 2a = c \)
H: \( 4a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 4 \)
\( 4(2) = 2d \Rightarrow 8 = 2d \Rightarrow d = 4 \)
\( 2 + 2b = 2(4) + 4 \Rightarrow 2 + 2b = 8 + 4 \Rightarrow 2 + 2b = 12 \Rightarrow 2b = 10 \Rightarrow b = 5 \)

Setara: 2CH3CHO + 5O2 → 4CO2 + 4H2O

CH3CH2CHO + O2 → CO2 + H2O
\( aC_3H_6O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 3a = c \)
H: \( 6a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 3 \)
\( 6 = 2d \Rightarrow d = 3 \)
\( 1 + 2b = 2(3) + 3 \Rightarrow 1 + 2b = 6 + 3 \Rightarrow 1 + 2b = 9 \Rightarrow 2b = 8 \Rightarrow b = 4 \)

Setara: CH3CH2CHO + 4O2 → 3CO2 + 3H2O

C6H13CHO + O2 → CO2 + H2O
\( aC_7H_{14}O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 14a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 7 \)
\( 14 = 2d \Rightarrow d = 7 \)
\( 1 + 2b = 2(7) + 7 \Rightarrow 1 + 2b = 14 + 7 \Rightarrow 1 + 2b = 21 \Rightarrow 2b = 20 \Rightarrow b = 10 \)

Setara: C6H13CHO + 10O2 → 7CO2 + 7H2O

C9H19CHO + O2 → CO2 + H2O
\( aC_{10}H_{20}O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 10a = c \)
H: \( 20a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 20 \)
\( 20(2) = 2d \Rightarrow 40 = 2d \Rightarrow d = 20 \)
\( 2 + 2b = 2(20) + 20 \Rightarrow 2 + 2b = 40 + 20 \Rightarrow 2 + 2b = 60 \Rightarrow 2b = 58 \Rightarrow b = 29 \)

Setara: 2C9H19CHO + 29O2 → 20CO2 + 20H2O

C6H5CHO + O2 → CO2 + H2O
\( aC_7H_6O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 7a = c \)
H: \( 6a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 7 \)
\( 6 = 2d \Rightarrow d = 3 \)
\( 1 + 2b = 2(7) + 3 \Rightarrow 1 + 2b = 14 + 3 \Rightarrow 1 + 2b = 17 \Rightarrow 2b = 16 \Rightarrow b = 8 \)

Setara: C6H5CHO + 8O2 → 7CO2 + 3H2O

C6H5COC2H5 + O2 → CO2 + H2O
\( aC_9H_{10}O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 9a = c \)
H: \( 10a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 9 \)
\( 10 = 2d \Rightarrow d = 5 \)
\( 1 + 2b = 2(9) + 5 \Rightarrow 1 + 2b = 18 + 5 \Rightarrow 1 + 2b = 23 \Rightarrow 2b = 22 \Rightarrow b = 11 \)

Setara: C6H5COC2H5 + 11O2 → 9CO2 + 5H2O

C2H2 + O2 → CO2 + H2O
\( aC_2H_2 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 2a = c \)
H: \( 2a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 4 \)
\( 2(2) = 2d \Rightarrow 4 = 2d \Rightarrow d = 2 \)
\( 2b = 2(4) + 2 \Rightarrow 2b = 8 + 2 \Rightarrow 2b = 10 \Rightarrow b = 5 \)

Setara: 2C2H2 + 5O2 → 4CO2 + 2H2O

C3H6 + O2 → CO2 + H2O
\( aC_3H_6 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 3a = c \)
H: \( 6a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 6 \)
\( 6(2) = 2d \Rightarrow 12 = 2d \Rightarrow d = 6 \)
\( 2b = 2(6) + 6 \Rightarrow 2b = 12 + 6 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: 2C3H6 + 9O2 → 6CO2 + 6H2O

C4H6 + O2 → CO2 + H2O
\( aC_4H_6 + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 4a = c \)
H: \( 6a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 8 \)
\( 6(2) = 2d \Rightarrow 12 = 2d \Rightarrow d = 6 \)
\( 2b = 2(8) + 6 \Rightarrow 2b = 16 + 6 \Rightarrow 2b = 22 \Rightarrow b = 11 \)

Setara: 2C4H6 + 11O2 → 8CO2 + 6H2O

C5H10 + O2 → CO2 + H2O
\( aC_5H_{10} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 5a = c \)
H: \( 10a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 10 \)
\( 10(2) = 2d \Rightarrow 20 = 2d \Rightarrow d = 10 \)
\( 2b = 2(10) + 10 \Rightarrow 2b = 20 + 10 \Rightarrow 2b = 30 \Rightarrow b = 15 \)

Setara: 2C5H10 + 15O2 → 10CO2 + 10H2O

C3H5OH + O2 → CO2 + H2O
\( aC_3H_6O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 3a = c \)
H: \( 6a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 3 \)
\( 6 = 2d \Rightarrow d = 3 \)
\( 1 + 2b = 2(3) + 3 \Rightarrow 1 + 2b = 6 + 3 \Rightarrow 1 + 2b = 9 \Rightarrow 2b = 8 \Rightarrow b = 4 \)

Setara: C3H5OH + 4O2 → 3CO2 + 3H2O

C3H7OH + O2 → CO2 + H2O
\( aC_3H_8O + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 3a = c \)
H: \( 8a = 2d \)
O: \( a + 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 6 \)
\( 8(2) = 2d \Rightarrow 16 = 2d \Rightarrow d = 8 \)
\( 2 + 2b = 2(6) + 8 \Rightarrow 2 + 2b = 12 + 8 \Rightarrow 2 + 2b = 20 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: 2C3H7OH + 9O2 → 6CO2 + 8H2O

C14H30 + O2 → CO2 + H2O
\( aC_{14}H_{30} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 14a = c \)
H: \( 30a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 28 \)
\( 30(2) = 2d \Rightarrow 60 = 2d \Rightarrow d = 30 \)
\( 2b = 2(28) + 30 \Rightarrow 2b = 56 + 30 \Rightarrow 2b = 86 \Rightarrow b = 43 \)

Setara: 2C14H30 + 43O2 → 28CO2 + 30H2O

C12H26 + O2 → CO2 + H2O
\( aC_{12}H_{26} + bO_2 \rightarrow cCO_2 + dH_2O \)
C: \( 12a = c \)
H: \( 26a = 2d \)
O: \( 2b = 2c + d \)
Misal \( a = 2 \)
\( c = 24 \)
\( 26(2) = 2d \Rightarrow 52 = 2d \Rightarrow d = 26 \)
\( 2b = 2(24) + 26 \Rightarrow 2b = 48 + 26 \Rightarrow 2b = 74 \Rightarrow b = 37 \)

Setara: 2C12H26 + 37O2 → 24CO2 + 26H2O

ZnS + O2 → ZnO + SO2
\( aZnS + bO_2 \rightarrow cZnO + dSO_2 \)
Zn: \( a = c \)
S: \( a = d \)
O: \( 2b = c + 2d \)
Misal \( a = 2 \)
\( c = 2, d = 2 \)
\( 2b = 2 + 2(2) \Rightarrow 2b = 2 + 4 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: 2ZnS + 3O2 → 2ZnO + 2SO2

PbS + O2 → PbO + SO2
\( aPbS + bO_2 \rightarrow cPbO + dSO_2 \)
Pb: \( a = c \)
S: \( a = d \)
O: \( 2b = c + 2d \)
Misal \( a = 2 \)
\( c = 2, d = 2 \)
\( 2b = 2 + 2(2) \Rightarrow 2b = 2 + 4 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: 2PbS + 3O2 → 2PbO + 2SO2

CuS + O2 → CuO + SO2
\( aCuS + bO_2 \rightarrow cCuO + dSO_2 \)
Cu: \( a = c \)
S: \( a = d \)
O: \( 2b = c + 2d \)
Misal \( a = 2 \)
\( c = 2, d = 2 \)
\( 2b = 2 + 2(2) \Rightarrow 2b = 2 + 4 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: 2CuS + 3O2 → 2CuO + 2SO2

Cu2S + O2 → Cu2O + SO2
\( aCu_2S + bO_2 \rightarrow cCu_2O + dSO_2 \)
Cu: \( 2a = 2c \)
S: \( a = d \)
O: \( 2b = c + 2d \)
Dari Cu: \( a = c \)
Misal \( a = 2 \)
\( c = 2, d = 2 \)
\( 2b = 2 + 2(2) \Rightarrow 2b = 2 + 4 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: 2Cu2S + 3O2 → 2Cu2O + 2SO2

Fe + H2O → Fe3O4 + H2
\( aFe + bH_2O \rightarrow cFe_3O_4 + dH_2 \)
Fe: \( a = 3c \)
H: \( 2b = 2d \)
O: \( b = 4c \)
Misal \( c = 1 \)
\( a = 3 \)
\( b = 4 \)
\( 2(4) = 2d \Rightarrow 8 = 2d \Rightarrow d = 4 \)

Setara: 3Fe + 4H2O → Fe3O4 + 4H2

SO2 + H2S → S + H2O
\( aSO_2 + bH_2S \rightarrow cS + dH_2O \)
S: \( a + b = c \)
O: \( 2a = d \)
H: \( 2b = 2d \)
Dari H: \( b = d \)
Dari O: \( 2a = b \)
Misal \( a = 1 \)
\( b = 2 \)
\( d = 2 \)
\( c = 1 + 2 = 3 \)

Setara: SO2 + 2H2S → 3S + 2H2O

PbS + H2O2 → PbSO4 + H2O
\( aPbS + bH_2O_2 \rightarrow cPbSO_4 + dH_2O \)
Pb: \( a = c \)
S: \( a = c \)
H: \( 2b = 2d \)
O: \( 2b = 4c + d \)
Misal \( a = 1 \)
\( c = 1 \)
Dari H: \( b = d \)
Dari O: \( 2b = 4 + b \Rightarrow b = 4 \)
Jadi \( b = 4, d = 4 \)

Setara: PbS + 4H2O2 → PbSO4 + 4H2O

Fe2O3 + CO → Fe3O4 + CO2
\( aFe_2O_3 + bCO \rightarrow cFe_3O_4 + dCO_2 \)
Fe: \( 2a = 3c \)
O: \( 3a + b = 4c + 2d \)
C: \( b = d \)
Misal \( c = 2 \)
\( 2a = 3(2) \Rightarrow 2a = 6 \Rightarrow a = 3 \)
\( b = d \)
Dari O: \( 3(3) + b = 4(2) + 2b \Rightarrow 9 + b = 8 + 2b \Rightarrow 9 - 8 = 2b - b \Rightarrow b = 1 \)
\( d = 1 \)

Setara: 3Fe2O3 + CO → 2Fe3O4 + CO2

Fe3O4 + Al → Al2O3 + Fe
\( aFe_3O_4 + bAl \rightarrow cAl_2O_3 + dFe \)
Fe: \( 3a = d \)
O: \( 4a = 3c \)
Al: \( b = 2c \)
Misal \( c = 4 \)
\( 4a = 3(4) \Rightarrow 4a = 12 \Rightarrow a = 3 \)
\( d = 3(3) = 9 \)
\( b = 2(4) = 8 \)

Setara: 3Fe3O4 + 8Al → 4Al2O3 + 9Fe

HNO3 + N2O3 + H2O → HNO2
\( aHNO_3 + bN_2O_3 + cH_2O \rightarrow dHNO_2 \)
H: \( a + 2c = d \)
N: \( a + 2b = d \)
O: \( 3a + 3b + c = 2d \)
Dari H dan N: \( a + 2c = a + 2b \Rightarrow 2c = 2b \Rightarrow c = b \)
Misal \( b = 1, c = 1 \)
\( a + 2(1) = d \) dan \( a + 2(1) = d \)
Misal \( a = 2 \)
\( d = 2 + 2 = 4 \)

Setara: 2HNO3 + N2O3 + H2O → 4HNO2

Fe + S + O2 → Fe2O3 + SO2
\( aFe + bS + cO_2 \rightarrow dFe_2O_3 + eSO_2 \)
Fe: \( a = 2d \)
S: \( b = e \)
O: \( 2c = 3d + 2e \)
Misal \( d = 2 \)
\( a = 4 \)
Misal \( b = 2 \)
\( e = 2 \)
\( 2c = 3(2) + 2(2) \Rightarrow 2c = 6 + 4 \Rightarrow 2c = 10 \Rightarrow c = 5 \)

Setara: 4Fe + 2S + 5O2 → 2Fe2O3 + 2SO2

Cu + S + O2 → Cu2O + SO2
\( aCu + bS + cO_2 \rightarrow dCu_2O + eSO_2 \)
Cu: \( a = 2d \)
S: \( b = e \)
O: \( 2c = d + 2e \)
Misal \( d = 2 \)
\( a = 4 \)
Misal \( b = 2 \)
\( e = 2 \)
\( 2c = 2 + 2(2) \Rightarrow 2c = 2 + 4 \Rightarrow 2c = 6 \Rightarrow c = 3 \)

Setara: 4Cu + 2S + 3O2 → 2Cu2O + 2SO2

FeS + O2 → Fe3O4 + SO2
\( aFeS + bO_2 \rightarrow cFe_3O_4 + dSO_2 \)
Fe: \( a = 3c \)
S: \( a = d \)
O: \( 2b = 4c + 2d \)
Misal \( c = 1 \)
\( a = 3, d = 3 \)
\( 2b = 4(1) + 2(3) \Rightarrow 2b = 4 + 6 \Rightarrow 2b = 10 \Rightarrow b = 5 \)

Setara: 3FeS + 5O2 → Fe3O4 + 3SO2

FeS + O2 → Fe2O3 + SO2
\( aFeS + bO_2 \rightarrow cFe_2O_3 + dSO_2 \)
Fe: \( a = 2c \)
S: \( a = d \)
O: \( 2b = 3c + 2d \)
Misal \( c = 2 \)
\( a = 4, d = 4 \)
\( 2b = 3(2) + 2(4) \Rightarrow 2b = 6 + 8 \Rightarrow 2b = 14 \Rightarrow b = 7 \)

Setara: 4FeS + 7O2 → 2Fe2O3 + 4SO2

FeS2 + O2 → Fe2O3 + SO2
\( aFeS_2 + bO_2 \rightarrow cFe_2O_3 + dSO_2 \)
Fe: \( a = 2c \)
S: \( 2a = d \)
O: \( 2b = 3c + 2d \)
Misal \( c = 2 \)
\( a = 4 \)
\( d = 2(4) = 8 \)
\( 2b = 3(2) + 2(8) \Rightarrow 2b = 6 + 16 \Rightarrow 2b = 22 \Rightarrow b = 11 \)

Setara: 4FeS2 + 11O2 → 2Fe2O3 + 8SO2

Fe2S3 + O2 → Fe2O3 + SO2
\( aFe_2S_3 + bO_2 \rightarrow cFe_2O_3 + dSO_2 \)
Fe: \( 2a = 2c \)
S: \( 3a = d \)
O: \( 2b = 3c + 2d \)
Dari Fe: \( a = c \)
Misal \( a = 2 \)
\( c = 2 \)
\( d = 3(2) = 6 \)
\( 2b = 3(2) + 2(6) \Rightarrow 2b = 6 + 12 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: 2Fe2S3 + 9O2 → 2Fe2O3 + 6SO2

ZnS + O2 → ZnO + SO2
\( aZnS + bO_2 \rightarrow cZnO + dSO_2 \)
Zn: \( a = c \)
S: \( a = d \)
O: \( 2b = c + 2d \)
Misal \( a = 2 \)
\( c = 2, d = 2 \)
\( 2b = 2 + 2(2) \Rightarrow 2b = 2 + 4 \Rightarrow 2b = 6 \Rightarrow b = 3 \)

Setara: 2ZnS + 3O2 → 2ZnO + 2SO2

Persamaan reaksi 5 spesi atau lebih

C5H5N + O2 → CO2 + H2O + N2
\( aC_5H_5N + bO_2 \rightarrow cCO_2 + dH_2O + eN_2 \)
C: \( 5a = c \)
H: \( 5a = 2d \)
N: \( a = 2e \)
O: \( 2b = 2c + d \)
Misal \( a = 4 \)
\( c = 20 \)
\( 5(4) = 2d \Rightarrow 20 = 2d \Rightarrow d = 10 \)
\( 4 = 2e \Rightarrow e = 2 \)
\( 2b = 2(20) + 10 \Rightarrow 2b = 40 + 10 \Rightarrow 2b = 50 \Rightarrow b = 25 \)

Setara: 4C5H5N + 25O2 → 20CO2 + 10H2O + 2N2

Cl2 + HClO + H2O → HCl + HClO2
\( aCl_2 + bHClO + cH_2O \rightarrow dHCl + eHClO_2 \)
Cl: \( 2a + b = d + e \)
H: \( b + 2c = d + e \)
O: \( b + c = 2e \)
Dari Cl dan H: \( 2a + b = b + 2c \Rightarrow 2a = 2c \Rightarrow a = c \)
Misal \( a = 1, c = 1 \)
\( 2 + b = d + e \)
\( b + 2 = d + e \)
\( b + 1 = 2e \)
Misal \( b = 1 \)
\( 1 + 1 = 2e \Rightarrow 2 = 2e \Rightarrow e = 1 \)
\( 2 + 1 = d + 1 \Rightarrow 3 = d + 1 \Rightarrow d = 2 \)

Setara: Cl2 + HClO + H2O → 2HCl + HClO2

CH3NH2 + O2 → CO2 + H2O + N2
\( aCH_3NH_2 + bO_2 \rightarrow cCO_2 + dH_2O + eN_2 \)
C: \( a = c \)
H: \( 5a = 2d \)
N: \( a = 2e \)
O: \( 2b = 2c + d \)
Misal \( a = 4 \)
\( c = 4 \)
\( 5(4) = 2d \Rightarrow 20 = 2d \Rightarrow d = 10 \)
\( 4 = 2e \Rightarrow e = 2 \)
\( 2b = 2(4) + 10 \Rightarrow 2b = 8 + 10 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: 4CH3NH2 + 9O2 → 4CO2 + 10H2O + 2N2

C2H5NH2 + O2 → CO2 + H2O + N2
\( aC_2H_5NH_2 + bO_2 \rightarrow cCO_2 + dH_2O + eN_2 \)
C: \( 2a = c \)
H: \( 7a = 2d \)
N: \( a = 2e \)
O: \( 2b = 2c + d \)
Misal \( a = 4 \)
\( c = 8 \)
\( 7(4) = 2d \Rightarrow 28 = 2d \Rightarrow d = 14 \)
\( 4 = 2e \Rightarrow e = 2 \)
\( 2b = 2(8) + 14 \Rightarrow 2b = 16 + 14 \Rightarrow 2b = 30 \Rightarrow b = 15 \)

Setara: 4C2H5NH2 + 15O2 → 8CO2 + 14H2O + 2N2

C6H5NH2 + O2 → CO2 + H2O + N2
\( aC_6H_5NH_2 + bO_2 \rightarrow cCO_2 + dH_2O + eN_2 \)
C: \( 6a = c \)
H: \( 7a = 2d \)
N: \( a = 2e \)
O: \( 2b = 2c + d \)
Misal \( a = 4 \)
\( c = 24 \)
\( 7(4) = 2d \Rightarrow 28 = 2d \Rightarrow d = 14 \)
\( 4 = 2e \Rightarrow e = 2 \)
\( 2b = 2(24) + 14 \Rightarrow 2b = 48 + 14 \Rightarrow 2b = 62 \Rightarrow b = 31 \)

Setara: 4C6H5NH2 + 31O2 → 24CO2 + 14H2O + 2N2

C3H5N + O2 → CO2 + H2O + N2
\( aC_3H_5N + bO_2 \rightarrow cCO_2 + dH_2O + eN_2 \)
C: \( 3a = c \)
H: \( 5a = 2d \)
N: \( a = 2e \)
O: \( 2b = 2c + d \)
Misal \( a = 4 \)
\( c = 12 \)
\( 5(4) = 2d \Rightarrow 20 = 2d \Rightarrow d = 10 \)
\( 4 = 2e \Rightarrow e = 2 \)
\( 2b = 2(12) + 10 \Rightarrow 2b = 24 + 10 \Rightarrow 2b = 34 \Rightarrow b = 17 \)

Setara: 4C3H5N + 17O2 → 12CO2 + 10H2O + 2N2

C7H5N + O2 → CO2 + H2O + N2
\( aC_7H_5N + bO_2 \rightarrow cCO_2 + dH_2O + eN_2 \)
C: \( 7a = c \)
H: \( 5a = 2d \)
N: \( a = 2e \)
O: \( 2b = 2c + d \)
Misal \( a = 4 \)
\( c = 28 \)
\( 5(4) = 2d \Rightarrow 20 = 2d \Rightarrow d = 10 \)
\( 4 = 2e \Rightarrow e = 2 \)
\( 2b = 2(28) + 10 \Rightarrow 2b = 56 + 10 \Rightarrow 2b = 66 \Rightarrow b = 33 \)

Setara: 4C7H5N + 33O2 → 28CO2 + 10H2O + 2N2

C5H11NH2 + O2 → CO2 + H2O + N2
\( aC_5H_{11}NH_2 + bO_2 \rightarrow cCO_2 + dH_2O + eN_2 \)
C: \( 5a = c \)
H: \( 13a = 2d \)
N: \( a = 2e \)
O: \( 2b = 2c + d \)
Misal \( a = 4 \)
\( c = 20 \)
\( 13(4) = 2d \Rightarrow 52 = 2d \Rightarrow d = 26 \)
\( 4 = 2e \Rightarrow e = 2 \)
\( 2b = 2(20) + 26 \Rightarrow 2b = 40 + 26 \Rightarrow 2b = 66 \Rightarrow b = 33 \)

Setara: 4C5H11NH2 + 33O2 → 20CO2 + 26H2O + 2N2

C4H8N2 + O2 → CO2 + H2O + N2
\( aC_4H_8N_2 + bO_2 \rightarrow cCO_2 + dH_2O + eN_2 \)
C: \( 4a = c \)
H: \( 8a = 2d \)
N: \( 2a = 2e \)
O: \( 2b = 2c + d \)
Misal \( a = 1 \)
\( c = 4 \)
\( 8 = 2d \Rightarrow d = 4 \)
\( 2 = 2e \Rightarrow e = 1 \)
\( 2b = 2(4) + 4 \Rightarrow 2b = 8 + 4 \Rightarrow 2b = 12 \Rightarrow b = 6 \)

Setara: C4H8N2 + 6O2 → 4CO2 + 4H2O + N2

Zn + HNO3 → Zn(NO3)2 + NO + H2O
\( aZn + bHNO_3 \rightarrow cZn(NO_3)_2 + dNO + eH_2O \)
Zn: \( a = c \)
H: \( b = 2e \)
N: \( b = 2c + d \)
O: \( 3b = 6c + d + e \)
Misal \( c = 3 \)
\( a = 3 \)
\( b = 2(3) + d = 6 + d \)
\( b = 2e \)
Misal \( d = 2 \)
\( b = 6 + 2 = 8 \)
\( 8 = 2e \Rightarrow e = 4 \)

Setara: 3Zn + 8HNO3 → 3Zn(NO3)2 + 2NO + 4H2O

FeS + O2 + H2O → Fe2O3 + H2SO4
\( aFeS + bO_2 + cH_2O \rightarrow dFe_2O_3 + eH_2SO_4 \)
Fe: \( a = 2d \)
S: \( a = e \)
O: \( 2b + c = 3d + 4e \)
H: \( 2c = 2e \)
Dari H: \( c = e \)
Misal \( a = 4 \)
\( d = 2, e = 4, c = 4 \)
\( 2b + 4 = 3(2) + 4(4) \Rightarrow 2b + 4 = 6 + 16 \Rightarrow 2b + 4 = 22 \Rightarrow 2b = 18 \Rightarrow b = 9 \)

Setara: 4FeS + 9O2 + 4H2O → 2Fe2O3 + 4H2SO4

Fe2S3 + O2 + H2O → Fe2O3 + H2SO4
\( aFe_2S_3 + bO_2 + cH_2O \rightarrow dFe_2O_3 + eH_2SO_4 \)
Fe: \( 2a = 2d \)
S: \( 3a = e \)
O: \( 2b + c = 3d + 4e \)
H: \( 2c = 2e \)
Dari Fe: \( a = d \)
Misal \( a = 1 \)
\( d = 1, e = 3, c = 3 \)
\( 2b + 3 = 3(1) + 4(3) \Rightarrow 2b + 3 = 3 + 12 \Rightarrow 2b + 3 = 15 \Rightarrow 2b = 12 \Rightarrow b = 6 \)

Setara: Fe2S3 + 6O2 + 3H2O → Fe2O3 + 3H2SO4

FeS2 + O2 + H2O → FeSO4 + H2SO4
\( aFeS_2 + bO_2 + cH_2O \rightarrow dFeSO_4 + eH_2SO_4 \)
Fe: \( a = d \)
S: \( 2a = d + e \)
O: \( 2b + c = 4d + 4e \)
H: \( 2c = 2e \)
Dari H: \( c = e \)
Dari S: \( 2a = a + e \Rightarrow a = e \)
Misal \( a = 2 \)
\( d = 2, e = 2, c = 2 \)
\( 2b + 2 = 4(2) + 4(2) \Rightarrow 2b + 2 = 8 + 8 \Rightarrow 2b + 2 = 16 \Rightarrow 2b = 14 \Rightarrow b = 7 \)

Setara: 2FeS2 + 7O2 + 2H2O → 2FeSO4 + 2H2SO4

PbS + HNO3 → Pb(NO3)2 + S + NO + H2O
\( aPbS + bHNO_3 \rightarrow cPb(NO_3)_2 + dS + eNO + fH_2O \)
Pb: \( a = c \)
S: \( a = d \)
H: \( b = 2f \)
N: \( b = 2c + e \)
O: \( 3b = 6c + e + f \)
Misal \( c = 3 \)
\( a = 3, d = 3 \)
\( b = 2(3) + e = 6 + e \)
\( b = 2f \)
Misal \( e = 2 \)
\( b = 6 + 2 = 8 \)
\( 8 = 2f \Rightarrow f = 4 \)

Setara: 3PbS + 8HNO3 → 3Pb(NO3)2 + 3S + 2NO + 4H2O

FeS + HNO3 → Fe(NO3)3 + H2SO4 + NO + H2O
\( aFeS + bHNO_3 \rightarrow cFe(NO_3)_3 + dH_2SO_4 + eNO + fH_2O \)
Fe: \( a = c \)
S: \( a = d \)
H: \( b = 2d + 2f \)
N: \( b = 3c + e \)
O: \( 3b = 9c + 4d + e + f \)
Misal \( a = 1 \)
\( c = 1, d = 1 \)
\( b = 3(1) + e = 3 + e \)
\( b = 2(1) + 2f = 2 + 2f \)
Dari dua persamaan: \( 3 + e = 2 + 2f \Rightarrow e = 2f - 1 \)
Misal \( f = 2 \)
\( e = 2(2) - 1 = 3 \)
\( b = 3 + 3 = 6 \)

Setara: FeS + 6HNO3 → Fe(NO3)3 + H2SO4 + 3NO + 2H2O

CuS + HNO3 → Cu(NO3)2 + H2SO4 + NO + H2O
\( aCuS + bHNO_3 \rightarrow cCu(NO_3)_2 + dH_2SO_4 + eNO + fH_2O \)
Cu: \( a = c \)
S: \( a = d \)
H: \( b = 2d + 2f \)
N: \( b = 2c + e \)
O: \( 3b = 6c + 4d + e + f \)
Misal \( a = 3 \)
\( c = 3, d = 3 \)
\( b = 2(3) + e = 6 + e \)
\( b = 2(3) + 2f = 6 + 2f \)
Dari dua persamaan: \( 6 + e = 6 + 2f \Rightarrow e = 2f \)
Misal \( f = 2 \)
\( e = 4 \)
\( b = 6 + 4 = 10 \)
Cek O: \( 3(10) = 6(3) + 4(3) + 4 + 2 \Rightarrow 30 = 18 + 12 + 4 + 2 \Rightarrow 30 = 36 \) (salah)
Perbaiki: Misal \( f = 4 \)
\( e = 8 \)
\( b = 6 + 8 = 14 \)
Cek O: \( 3(14) = 6(3) + 4(3) + 8 + 4 \Rightarrow 42 = 18 + 12 + 8 + 4 \Rightarrow 42 = 42 \) ✓
Tapi perlu perhatikan: koefisien harus bilangan bulat terkecil
Bagi semua dengan 2: \( a = 3, c = 3, d = 3, e = 2, f = 4, b = 8 \)

Setara: 3CuS + 8HNO3 → 3Cu(NO3)2 + 3H2SO4 + 2NO + 4H2O

CuS + HNO3 → CuSO4 + NO2 + H2O
\( aCuS + bHNO_3 \rightarrow cCuSO_4 + dNO_2 + eH_2O \)
Cu: \( a = c \)
S: \( a = c \)
H: \( b = 2e \)
N: \( b = d \)
O: \( 3b = 4c + 2d + e \)
Misal \( a = 1 \)
\( c = 1 \)
\( b = d = 2e \)
\( 3b = 4(1) + 2b + \dfrac{b}{2} \Rightarrow 3b = 4 + 2b + 0.5b \Rightarrow 3b - 2.5b = 4 \Rightarrow 0.5b = 4 \Rightarrow b = 8 \)
\( d = 8, e = 4 \)

Setara: CuS + 8HNO3 → CuSO4 + 8NO2 + 4H2O

FeS + HNO3 → Fe(NO3)3 + H2SO4 + NO
\( aFeS + bHNO_3 \rightarrow cFe(NO_3)_3 + dH_2SO_4 + eNO \)
Fe: \( a = c \)
S: \( a = d \)
H: \( b = 2d \)
N: \( b = 3c + e \)
O: \( 3b = 9c + 4d + e \)
Dari Fe dan S: \( a = c = d \)
Misal \( a = 1 \)
\( c = 1, d = 1 \)
Dari H: \( b = 2(1) = 2 \)
Dari N: \( 2 = 3(1) + e \)
\( 2 = 3 + e \)
\( e = -1 \) (tidak mungkin, harus positif)
Artinya perlu H2O di kanan:
\( aFeS + bHNO_3 \rightarrow cFe(NO_3)_3 + dH_2SO_4 + eNO + fH_2O \)
Fe: \( a = c \)
S: \( a = d \)
H: \( b = 2d + 2f \)
N: \( b = 3c + e \)
O: \( 3b = 9c + 4d + e + f \)
Misal \( a = 1 \)
\( c = 1, d = 1 \)
Dari H: \( b = 2 + 2f \)
Dari N: \( b = 3 + e \)
Jadi \( 2 + 2f = 3 + e \)
\( e = 2f - 1 \)
Dari O: \( 3b = 9 + 4 + e + f = 13 + e + f \)
Substitusi \( b = 2 + 2f \):
\( 3(2 + 2f) = 13 + (2f - 1) + f \)
\( 6 + 6f = 13 + 2f - 1 + f \)
\( 6 + 6f = 12 + 3f \)
\( 3f = 6 \)
\( f = 2 \)
\( e = 2(2) - 1 = 4 - 1 = 3 \)
\( b = 2 + 2(2) = 2 + 4 = 6 \)
Cek semua:
Fe: 1 = 1 ✓
S: 1 = 1 ✓
H: 6 = 2×1 + 2×2 = 2 + 4 = 6 ✓
N: 6 = 3×1 + 3 = 3 + 3 = 6 ✓
O: 3×6 = 18, kanan: 9×1 + 4×1 + 3 + 2 = 9 + 4 + 3 + 2 = 18 ✓

Setara: FeS + 6HNO3 → Fe(NO3)3 + H2SO4 + 3NO + 2H2O

FeS2 + HNO3 → Fe(NO3)3 + H2SO4 + NO + H2O
\( aFeS_2 + bHNO_3 \rightarrow cFe(NO_3)_3 + dH_2SO_4 + eNO + fH_2O \)
Fe: \( a = c \)
S: \( 2a = d \)
H: \( b = 2d + 2f \)
N: \( b = 3c + e \)
O: \( 3b = 9c + 4d + e + f \)
Misal \( a = 1 \)
\( c = 1, d = 2 \)
\( b = 3(1) + e = 3 + e \)
\( b = 2(2) + 2f = 4 + 2f \)
Dari dua persamaan: \( 3 + e = 4 + 2f \Rightarrow e = 1 + 2f \)
Misal \( f = 2 \)
\( e = 1 + 4 = 5 \)
\( b = 3 + 5 = 8 \)

Setara: FeS2 + 8HNO3 → Fe(NO3)3 + 2H2SO4 + 5NO + 2H2O

Pb3O4 + HNO3 → Pb(NO3)2 + O2 + H2O
\( aPb_3O_4 + bHNO_3 \rightarrow cPb(NO_3)_2 + dO_2 + eH_2O \)
Pb: \( 3a = c \)
O: \( 4a + 3b = 6c + 2d + e \)
H: \( b = 2e \)
N: \( b = 2c \)
Dari N: \( b = 2c \)
Dari H: \( 2c = 2e \Rightarrow c = e \)
Misal \( a = 2 \)
\( c = 6, e = 6, b = 12 \)
Dari O: \( 4(2) + 3(12) = 6(6) + 2d + 6 \Rightarrow 8 + 36 = 36 + 2d + 6 \Rightarrow 44 = 42 + 2d \Rightarrow 2d = 2 \Rightarrow d = 1 \)

Setara: 2Pb3O4 + 12HNO3 → 6Pb(NO3)2 + O2 + 6H2O

Zn + HNO3 + O2 → Zn(NO3)2 + NO + H2O
\( aZn + bHNO_3 + cO_2 \rightarrow dZn(NO_3)_2 + eNO + fH_2O \)
Zn: \( a = d \)
H: \( b = 2f \)
N: \( b = 2d + e \)
O: \( 3b + 2c = 6d + e + f \)
Misal \( d = 4 \)
\( a = 4 \)
\( b = 2(4) + e = 8 + e \)
\( b = 2f \)
Misal \( e = 1 \) (untuk NO, tapi biasanya N2O)
Perhatikan: reaksi sebenarnya menghasilkan N2O
Untuk Zn + HNO3 → Zn(NO3)2 + N2O + H2O
\( 4Zn + 10HNO_3 \rightarrow 4Zn(NO_3)_2 + N_2O + 5H_2O \)

Setara: 4Zn + 10HNO3 → 4Zn(NO3)2 + N2O + 5H2O

Cu + HNO3 + O2 → Cu(NO3)2 + NO + H2O
\( aCu + bHNO_3 + cO_2 \rightarrow dCu(NO_3)_2 + eNO + fH_2O \)
Cu: \( a = d \)
H: \( b = 2f \)
N: \( b = 2d + e \)
O: \( 3b + 2c = 6d + e + f \)
Dari H: \( b = 2f \)
Dari N: \( 2f = 2d + e \)
Dari O: \( 3(2f) + 2c = 6d + e + f \Rightarrow 6f + 2c = 6d + e + f \Rightarrow 5f + 2c = 6d + e \)
Substitusi \( e = 2f - 2d \) ke persamaan O:
\( 5f + 2c = 6d + (2f - 2d) \)
\( 5f + 2c = 4d + 2f \)
\( 3f + 2c = 4d \)
Coba dengan bilangan bulat:
Misal \( d = 7 \) (dari setara yang diberikan)
\( a = 7 \)
\( 3f + 2c = 4(7) = 28 \)
Coba \( e = 2 \) (dari setara yang diberikan)
Dari N: \( b = 2(7) + 2 = 14 + 2 = 16 \)
Dari H: \( 16 = 2f \Rightarrow f = 8 \)
Dari O: \( 3(16) + 2c = 6(7) + 2 + 8 \)
\( 48 + 2c = 42 + 2 + 8 = 52 \)
\( 2c = 4 \Rightarrow c = 2 \)
Cek semua:
Cu: 7 = 7 ✓
H: 16 = 2×8 = 16 ✓
N: 16 = 2×7 + 2 = 14 + 2 = 16 ✓
O: 3×16 + 2×2 = 48 + 4 = 52, kanan: 6×7 + 2 + 8 = 42 + 2 + 8 = 52 ✓

Setara: 7Cu + 16HNO3 + 2O2 → 7Cu(NO3)2 + 2NO + 8H2O

Cu + H2SO4 + O2 → CuSO4 + SO2 + H2O
\( aCu + bH_2SO_4 + cO_2 \rightarrow dCuSO_4 + eSO_2 + fH_2O \)
Cu: \( a = d \)
S: \( b = d + e \)
O: \( 4b + 2c = 4d + 2e + f \)
H: \( 2b = 2f \)
Dari H: \( b = f \)
Misal \( a = 2 \)
\( d = 2 \)
\( b = 2 + e \)
\( b = f \)
Misal \( e = 0 \) (tidak ada SO2)
\( b = 2, f = 2 \)
Dari O: \( 4(2) + 2c = 4(2) + 0 + 2 \Rightarrow 8 + 2c = 8 + 2 \Rightarrow 2c = 2 \Rightarrow c = 1 \)

Setara: 2Cu + 2H2SO4 + O2 → 2CuSO4 + 2H2O

Ag + H2SO4 + O2 → Ag2SO4 + SO2 + H2O
\( aAg + bH_2SO_4 + cO_2 \rightarrow dAg_2SO_4 + eSO_2 + fH_2O \)
Ag: \( a = 2d \)
S: \( b = d + e \)
O: \( 4b + 2c = 4d + 2e + f \)
H: \( 2b = 2f \)
Dari H: \( b = f \)
Misal \( d = 2 \)
\( a = 4 \)
\( b = 2 + e \)
\( b = f \)
Misal \( e = 0 \)
\( b = 2, f = 2 \)
Dari O: \( 4(2) + 2c = 4(2) + 0 + 2 \Rightarrow 8 + 2c = 8 + 2 \Rightarrow 2c = 2 \Rightarrow c = 1 \)

Setara: 4Ag + 2H2SO4 + O2 → 2Ag2SO4 + 2H2O

Pb + H2SO4 → PbSO4 + SO2 + H2O
\( aPb + bH_2SO_4 \rightarrow cPbSO_4 + dSO_2 + eH_2O \)
Pb: \( a = c \)
S: \( b = c + d \)
O: \( 4b = 4c + 2d + e \)
H: \( 2b = 2e \)
Dari H: \( b = e \)
Misal \( a = 1 \)
\( c = 1 \)
\( b = 1 + d \)
\( b = e \)
Misal \( d = 1 \)
\( b = 2, e = 2 \)
Cek O: \( 4(2) = 4(1) + 2(1) + 2 \Rightarrow 8 = 4 + 2 + 2 \Rightarrow 8 = 8 \) ✓

Setara: Pb + 2H2SO4 → PbSO4 + SO2 + 2H2O

Pb + PbO2 + H2SO4 → PbSO4 + H2O
\( aPb + bPbO_2 + cH_2SO_4 \rightarrow dPbSO_4 + eH_2O \)
Pb: \( a + b = d \)
O: \( 2b + 4c = 4d + e \)
S: \( c = d \)
H: \( 2c = 2e \)
Dari H: \( c = e \)
Dari S: \( c = d \)
Misal \( c = 2 \)
\( d = 2, e = 2 \)
\( a + b = 2 \)
\( 2b + 4(2) = 4(2) + 2 \Rightarrow 2b + 8 = 8 + 2 \Rightarrow 2b = 2 \Rightarrow b = 1 \)
\( a = 1 \)

Setara: Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O

MnO2 + Mn + H2SO4 → MnSO4 + H2O
\( aMnO_2 + bMn + cH_2SO_4 \rightarrow dMnSO_4 + eH_2O \)
Mn: \( a + b = d \)
O: \( 2a + 4c = 4d + e \)
S: \( c = d \)
H: \( 2c = 2e \)
Dari H: \( c = e \)
Dari S: \( c = d \)
Misal \( c = 2 \)
\( d = 2, e = 2 \)
\( a + b = 2 \)
\( 2a + 4(2) = 4(2) + 2 \Rightarrow 2a + 8 = 8 + 2 \Rightarrow 2a = 2 \Rightarrow a = 1 \)
\( b = 1 \)

Setara: MnO2 + Mn + 2H2SO4 → 2MnSO4 + 2H2O

Pb + H2SO4 + O2 → PbSO4 + SO2 + H2O
\( aPb + bH_2SO_4 + cO_2 \rightarrow dPbSO_4 + eSO_2 + fH_2O \)
Pb: \( a = d \)
S: \( b = d + e \)
O: \( 4b + 2c = 4d + 2e + f \)
H: \( 2b = 2f \)
Dari H: \( b = f \)
Dari S: \( b = a + e \) (karena \( d = a \))
Jadi \( f = a + e \)
Dari O: \( 4b + 2c = 4a + 2e + f \)
Substitusi \( b = f \):
\( 4f + 2c = 4a + 2e + f \)
\( 3f + 2c = 4a + 2e \)
Substitusi \( f = a + e \):
\( 3(a + e) + 2c = 4a + 2e \)
\( 3a + 3e + 2c = 4a + 2e \)
\( 3e + 2c = a + 2e \)
\( e + 2c = a \)
Coba \( c = 1 \)
\( e + 2 = a \)
Coba \( e = 1 \)
\( 1 + 2 = a \Rightarrow a = 3 \)
\( d = 3 \)
\( b = 3 + 1 = 4 \)
\( f = 4 \)
Cek semua:
Pb: 3 = 3 ✓
S: 4 = 3 + 1 = 4 ✓
O: 4×4 + 2×1 = 16 + 2 = 18, kanan: 4×3 + 2×1 + 4 = 12 + 2 + 4 = 18 ✓
H: 2×4 = 8, kanan: 2×4 = 8 ✓

Setara: 3Pb + 4H2SO4 + O2 → 3PbSO4 + SO2 + 4H2O

FeS + H2SO4 + O2 → Fe2(SO4)3 + H2O
\( aFeS + bH_2SO_4 + cO_2 \rightarrow dFe_2(SO_4)_3 + eH_2O \)
Fe: \( a = 2d \)
S: \( a + b = 3d \)
O: \( 4b + 2c = 12d + e \)
H: \( 2b = 2e \)
Dari H: \( b = e \)
Misal \( d = 2 \)
\( a = 4 \)
\( 4 + b = 3(2) \Rightarrow 4 + b = 6 \Rightarrow b = 2 \)
\( e = 2 \)
\( 4(2) + 2c = 12(2) + 2 \Rightarrow 8 + 2c = 24 + 2 \Rightarrow 2c = 18 \Rightarrow c = 9 \)

Setara: 4FeS + 2H2SO4 + 9O2 → 2Fe2(SO4)3 + 2H2O

Fe2O3 + H2S + H2 → FeS + H2O
\( aFe_2O_3 + bH_2S + cH_2 \rightarrow dFeS + eH_2O \)
Fe: \( 2a = d \)
O: \( 3a = e \)
H: \( 2b + 2c = 2e \)
S: \( b = d \)
Dari Fe dan S: \( 2a = d = b \)
Misal \( a = 1 \)
\( d = 2, b = 2 \)
\( e = 3(1) = 3 \)
Dari H: \( 2(2) + 2c = 2(3) \)
\( 4 + 2c = 6 \)
\( 2c = 2 \)
\( c = 1 \)
Cek semua:
Fe: 2×1 = 2 ✓
O: 3×1 = 3 ✓
H: 2×2 + 2×1 = 4 + 2 = 6, kanan: 2×3 = 6 ✓
S: 2 = 2 ✓

Setara: Fe2O3 + 2H2S + H2 → 2FeS + 3H2O

Fe2O3 + H2S + O2 → FeS + SO2 + H2O
\( aFe_2O_3 + bH_2S + cO_2 \rightarrow dFeS + eSO_2 + fH_2O \)
Fe: \( 2a = d \)
O: \( 3a + 2c = 2e + f \)
H: \( 2b = 2f \)
S: \( b = d + e \)
Dari H: \( b = f \)
Misal \( a = 1 \)
\( d = 2 \)
Dari S: \( b = 2 + e \)
Dari O: \( 3(1) + 2c = 2e + b \)
Substitusi \( b = 2 + e \):
\( 3 + 2c = 2e + (2 + e) \)
\( 3 + 2c = 2e + 2 + e \)
\( 3 + 2c = 3e + 2 \)
\( 2c = 3e - 1 \)
Coba \( e = 1 \)
\( 2c = 3(1) - 1 = 2 \)
\( c = 1 \)
\( b = 2 + 1 = 3 \)
\( f = 3 \)
Cek semua:
Fe: 2×1 = 2 ✓
O: 3×1 + 2×1 = 3 + 2 = 5, kanan: 2×1 + 3 = 2 + 3 = 5 ✓
H: 2×3 = 6, kanan: 2×3 = 6 ✓
S: 3 = 2 + 1 = 3 ✓

Setara: Fe2O3 + 3H2S + O2 → 2FeS + SO2 + 3H2O

Fe3O4 + H2S → FeS + S + H2O
\( aFe_3O_4 + bH_2S \rightarrow cFeS + dS + eH_2O \)
Fe: \( 3a = c \)
O: \( 4a = e \)
H: \( 2b = 2e \)
S: \( b = c + d \)
Dari H: \( b = e \)
Dari O: \( e = 4a \)
Jadi \( b = 4a \)
Dari Fe: \( c = 3a \)
Dari S: \( 4a = 3a + d \)
\( d = a \)
Misal \( a = 1 \)
\( c = 3, d = 1, e = 4, b = 4 \)
Cek semua:
Fe: 3×1 = 3 ✓
O: 4×1 = 4 ✓
H: 2×4 = 8, kanan: 2×4 = 8 ✓
S: 4 = 3 + 1 = 4 ✓

Setara: Fe3O4 + 4H2S → 3FeS + S + 4H2O

Fe3O4 + H2S + O2 → FeSO4 + S + H2O
\( aFe_3O_4 + bH_2S + cO_2 \rightarrow dFeSO_4 + eS + fH_2O \)
Fe: \( 3a = d \)
O: \( 4a + 2c = 4d + f \)
H: \( 2b = 2f \)
S: \( b = d + e \)
Dari H: \( b = f \)
Misal \( a = 1 \)
\( d = 3 \)
Dari S: \( b = 3 + e \)
Dari O: \( 4(1) + 2c = 4(3) + b \)
\( 4 + 2c = 12 + b \)
\( 2c = 8 + b \)
Substitusi \( b = 3 + e \):
\( 2c = 8 + (3 + e) \)
\( 2c = 11 + e \)
Coba \( e = 1 \)
\( 2c = 11 + 1 = 12 \)
\( c = 6 \)
\( b = 3 + 1 = 4 \)
\( f = 4 \)
Cek semua:
Fe: 3×1 = 3 ✓
O: 4×1 + 2×6 = 4 + 12 = 16, kanan: 4×3 + 4 = 12 + 4 = 16 ✓
H: 2×4 = 8, kanan: 2×4 = 8 ✓
S: 4 = 3 + 1 = 4 ✓

Setara: Fe3O4 + 4H2S + 6O2 → 3FeSO4 + S + 4H2O

Zn + HNO3 + H2SO4 → ZnSO4 + NO2 + H2O
\( aZn + bHNO_3 + cH_2SO_4 \rightarrow dZnSO_4 + eNO_2 + fH_2O \)
Zn: \( a = d \)
S: \( c = d \)
H: \( b + 2c = 2f \)
N: \( b = e \)
O: \( 3b + 4c = 4d + 2e + f \)
Misal \( a = 1 \)
\( d = 1, c = 1 \)
\( b = e \)
\( b + 2(1) = 2f \Rightarrow b + 2 = 2f \)
\( 3b + 4(1) = 4(1) + 2b + f \Rightarrow 3b + 4 = 4 + 2b + f \Rightarrow b = f \)
\( b + 2 = 2b \Rightarrow 2 = b \)
\( e = 2, f = 2 \)

Setara: Zn + 2HNO3 + H2SO4 → ZnSO4 + 2NO2 + 2H2O

CuS + HNO3 → Cu(NO3)2 + NO2 + S8 + H2O
\( aCuS + bHNO_3 \rightarrow cCu(NO_3)_2 + dNO_2 + eS_8 + fH_2O \)
Cu: \( a = c \)
S: \( a = 8e \)
H: \( b = 2f \)
N: \( b = 2c + d \)
O: \( 3b = 6c + 2d + f \)
Dari S: \( a = 8e \)
Misal \( e = 1 \)
\( a = 8, c = 8 \)
Dari N: \( b = 2(8) + d = 16 + d \)
Dari H: \( b = 2f \)
Dari O: \( 3b = 6(8) + 2d + f = 48 + 2d + f \)
Substitusi \( b = 16 + d \) dan \( f = b/2 = (16 + d)/2 \):
\( 3(16 + d) = 48 + 2d + \dfrac{16 + d}{2} \)
\( 48 + 3d = 48 + 2d + 8 + 0.5d \)
\( 48 + 3d = 56 + 2.5d \)
\( 0.5d = 8 \)
\( d = 16 \)
\( b = 16 + 16 = 32 \)
\( f = 32/2 = 16 \)
Cek semua:
Cu: 8 = 8 ✓
S: 8 = 8×1 = 8 ✓
H: 32 = 2×16 = 32 ✓
N: 32 = 2×8 + 16 = 16 + 16 = 32 ✓
O: 3×32 = 96, kanan: 6×8 + 2×16 + 16 = 48 + 32 + 16 = 96 ✓

Setara: 8CuS + 32HNO3 → 8Cu(NO3)2 + 16NO2 + S8 + 16H2O

FeS2 + HNO3 + H2O → Fe(NO3)3 + H2SO4 + NO2 + H2O
\( aFeS_2 + bHNO_3 + cH_2O \rightarrow dFe(NO_3)_3 + eH_2SO_4 + fNO_2 + gH_2O \)
Fe: \( a = d \)
S: \( 2a = e \)
H: \( b + 2c = 2e + 2g \)
N: \( b = 3d + f \)
O: \( 3b + c = 9d + 4e + 2f + g \)
Misal \( a = 1 \)
\( d = 1, e = 2 \)
Dari N: \( b = 3(1) + f = 3 + f \)
Dari H: \( (3 + f) + 2c = 2(2) + 2g = 4 + 2g \)
\( 3 + f + 2c = 4 + 2g \)
\( f + 2c = 1 + 2g \)
Dari O: \( 3(3 + f) + c = 9(1) + 4(2) + 2f + g \)
\( 9 + 3f + c = 9 + 8 + 2f + g \)
\( 9 + 3f + c = 17 + 2f + g \)
\( f + c = 8 + g \)
Kita punya:
1) \( f + 2c = 1 + 2g \)
2) \( f + c = 8 + g \)
Kurangkan (2) dari (1):
\( (f + 2c) - (f + c) = (1 + 2g) - (8 + g) \)
\( c = -7 + g \)
Substitusi ke (2):
\( f + (-7 + g) = 8 + g \)
\( f - 7 + g = 8 + g \)
\( f = 15 \)
\( b = 3 + 15 = 18 \)
Dari \( c = -7 + g \), pilih \( g = 7 \) agar \( c = 0 \) (H_2O di kiri bisa 0)
\( c = 0 \)
Cek semua:
Fe: 1 = 1 ✓
S: 2×1 = 2 ✓
H: 18 + 0 = 18, kanan: 2×2 + 2×7 = 4 + 14 = 18 ✓
N: 18 = 3×1 + 15 = 3 + 15 = 18 ✓
O: 3×18 + 0 = 54, kanan: 9×1 + 4×2 + 2×15 + 7 = 9 + 8 + 30 + 7 = 54 ✓

Setara: FeS2 + 18HNO3 → Fe(NO3)3 + 2H2SO4 + 15NO2 + 7H2O

CuFeS2 + HNO3 + O2 → Cu(NO3)2 + Fe(NO3)3 + SO2 + H2O
\( aCuFeS_2 + bHNO_3 + cO_2 \rightarrow dCu(NO_3)_2 + eFe(NO_3)_3 + fSO_2 + gH_2O \)
Cu: \( a = d \)
Fe: \( a = e \)
S: \( 2a = f \)
H: \( b = 2g \)
N: \( b = 2d + 3e \)
O: \( 3b + 2c = 6d + 9e + 2f + g \)
Misal \( a = 4 \)
\( d = 4, e = 4, f = 8 \)
Dari N: \( b = 2(4) + 3(4) = 8 + 12 = 20 \)
Dari H: \( 20 = 2g \Rightarrow g = 10 \)
Dari O: \( 3(20) + 2c = 6(4) + 9(4) + 2(8) + 10 \)
\( 60 + 2c = 24 + 36 + 16 + 10 \)
\( 60 + 2c = 86 \)
\( 2c = 26 \)
\( c = 13 \)
Cek semua:
Cu: 4 = 4 ✓
Fe: 4 = 4 ✓
S: 2×4 = 8 ✓
H: 20 = 2×10 = 20 ✓
N: 20 = 2×4 + 3×4 = 8 + 12 = 20 ✓
O: 3×20 + 2×13 = 60 + 26 = 86, kanan: 6×4 + 9×4 + 2×8 + 10 = 24 + 36 + 16 + 10 = 86 ✓

Setara: 4CuFeS2 + 20HNO3 + 13O2 → 4Cu(NO3)2 + 4Fe(NO3)3 + 8SO2 + 10H2O

CuFeS2 + HNO3 → Cu(NO3)2 + Fe(NO3)3 + S + NO + H2O
\( aCuFeS_2 + bHNO_3 \rightarrow cCu(NO_3)_2 + dFe(NO_3)_3 + eS + fNO + gH_2O \)
Cu: \( a = c \)
Fe: \( a = d \)
S: \( 2a = e \)
H: \( b = 2g \)
N: \( b = 2c + 3d + f \)
O: \( 3b = 6c + 9d + f + g \)
Misal \( a = 3 \)
\( c = 3, d = 3, e = 6 \)
\( b = 2(3) + 3(3) + f = 6 + 9 + f = 15 + f \)
\( b = 2g \)
Misal \( f = 5 \)
\( b = 20, g = 10 \)
Cek O: \( 3(20) = 6(3) + 9(3) + 5 + 10 \Rightarrow 60 = 18 + 27 + 5 + 10 \Rightarrow 60 = 60 \) ✓

Setara: 3CuFeS2 + 20HNO3 → 3Cu(NO3)2 + 3Fe(NO3)3 + 6S + 5NO + 10H2O

CuFeS2 + O2 → Cu + Fe2O3 + SO2
\( aCuFeS_2 + bO_2 \rightarrow cCu + dFe_2O_3 + eSO_2 \)
Cu: \( a = c \)
Fe: \( a = 2d \)
S: \( 2a = e \)
O: \( 2b = 3d + 2e \)
Dari Fe: \( a = 2d \Rightarrow d = \dfrac{a}{2} \)
Dari S: \( e = 2a \)
Dari O: \( 2b = 3\left(\dfrac{a}{2}\right) + 2(2a) \)
\( 2b = \dfrac{3a}{2} + 4a \)
\( 2b = \dfrac{3a}{2} + \dfrac{8a}{2} = \dfrac{11a}{2} \)
\( b = \dfrac{11a}{4} \)
Agar \( b \) bulat, pilih \( a = 4 \)
\( c = 4 \)
\( d = \dfrac{4}{2} = 2 \)
\( e = 2(4) = 8 \)
\( b = \dfrac{11 \times 4}{4} = 11 \)
Cek semua:
Cu: 4 = 4 ✓
Fe: 4 = 2×2 = 4 ✓
S: 2×4 = 8 ✓
O: 2×11 = 22, kanan: 3×2 + 2×8 = 6 + 16 = 22 ✓

Setara: 4CuFeS2 + 11O2 → 4Cu + 2Fe2O3 + 8SO2

PbS + H2O2 + H2SO4 → PbSO4 + SO2 + H2O
\( aPbS + bH_2O_2 + cH_2SO_4 \rightarrow dPbSO_4 + eSO_2 + fH_2O \)
Pb: \( a = d \)
S: \( a + c = d + e \)
O: \( 2b + 4c = 4d + 2e + f \)
H: \( 2b + 2c = 2f \)
Misal \( a = 2 \)
\( d = 2 \)
Misal \( e = 1 \)
\( 2 + c = 2 + 1 \Rightarrow c = 1 \)
\( 2b + 2(1) = 2f \Rightarrow 2b + 2 = 2f \Rightarrow b + 1 = f \)
\( 2b + 4(1) = 4(2) + 2(1) + f \Rightarrow 2b + 4 = 8 + 2 + f \Rightarrow 2b + 4 = 10 + f \)
Substitusi \( f = b + 1 \):
\( 2b + 4 = 10 + b + 1 \Rightarrow b = 7 \)
\( f = 8 \)

Setara: 2PbS + 7H2O2 + H2SO4 → 2PbSO4 + SO2 + 8H2O

Cu2S + HNO3 → Cu(NO3)2 + NO + S + H2O
\( aCu_2S + bHNO_3 \rightarrow cCu(NO_3)_2 + dNO + eS + fH_2O \)
Cu: \( 2a = c \)
S: \( a = e \)
H: \( b = 2f \)
N: \( b = 2c + d \)
O: \( 3b = 6c + d + f \)
Dari S: \( e = a \)
Dari Cu: \( c = 2a \)
Substitusi ke persamaan N:
\( b = 2c + d \)
\( b = 2(2a) + d \)
\( b = 4a + d \)      (1)
Dari H: \( b = 2f \)
Substitusi ke persamaan O:
\( 3(4a + d) = 6(2a) + d + \dfrac{4a + d}{2} \)
\( 12a + 3d = 12a + d + 2a + \dfrac{d}{2} \)
\( 3d = d + 2a + \dfrac{d}{2} \)
\( 3d = 2a + \dfrac{3d}{2} \)
\( \dfrac{3d}{2} = 2a \)
\( 3d = 4a \)
\( a = \dfrac{3}{4}d \)      (2)
Ambil bilangan bulat terkecil. Pilih \( d = 4 \) dari persamaan (2):
\( a = \dfrac{3}{4} \times 4 = 3 \)
\( a = 3 \)
\( c = 2a = 6 \)
\( e = a = 3 \)
Dari persamaan (1):
\( b = 4a + d = 4(3) + 4 = 12 + 4 = 16 \)
Dari persamaan H:
\( b = 2f \)
\( 16 = 2f \)
\( f = 8 \)
Mengecek keseimbangan semua atom:
Cu: Reaktan = \( 2a = 6 \), Produk = \( c = 6 \) ✓
S: Reaktan = \( a = 3 \), Produk = \( e = 3 \) ✓
H: Reaktan = \( b = 16 \), Produk = \( 2f = 16 \) ✓
N: Reaktan = \( b = 16 \), Produk = \( 2c + d = 12 + 4 = 16 \) ✓
O: Reaktan = \( 3b = 48 \), Produk = \( 6c + d + f = 36 + 4 + 8 = 48 \) ✓

Persamaan reaksi setara: \( 3Cu_2S + 16HNO_3 \rightarrow 6Cu(NO_3)_2 + 4NO + 3S + 8H_2O \)

ZnS + HNO3 + O2 → Zn(NO3)2 + H2SO4 + NO2 + H2O
\( aZnS + bHNO_3 + cO_2 \rightarrow dZn(NO_3)_2 + eH_2SO_4 + fNO_2 + gH_2O \)
Zn: \( a = d \)
S: \( a = e \)
H: \( b = 2e + 2g \)
N: \( b = 2d + f \)
O: \( 3b + 2c = 6d + 4e + 2f + g \)
Misal \( a = 5 \)
\( d = 5, e = 5 \)
Dari N: \( b = 2(5) + f = 10 + f \)
Dari H: \( b = 2(5) + 2g = 10 + 2g \)
Jadi \( 10 + f = 10 + 2g \Rightarrow f = 2g \)
Dari O: \( 3(10 + f) + 2c = 6(5) + 4(5) + 2f + g \)
\( 30 + 3f + 2c = 30 + 20 + 2f + g \)
\( 30 + 3f + 2c = 50 + 2f + g \)
\( f + 2c = 20 + g \)
Substitusi \( f = 2g \):
\( 2g + 2c = 20 + g \)
\( g + 2c = 20 \)
Coba \( c = 8 \)
\( g + 16 = 20 \Rightarrow g = 4 \)
\( f = 2(4) = 8 \)
\( b = 10 + 8 = 18 \)
Cek semua:
Zn: 5 = 5 ✓
S: 5 = 5 ✓
H: 18 = 2×5 + 2×4 = 10 + 8 = 18 ✓
N: 18 = 2×5 + 8 = 10 + 8 = 18 ✓
O: 3×18 + 2×8 = 54 + 16 = 70, kanan: 6×5 + 4×5 + 2×8 + 4 = 30 + 20 + 16 + 4 = 70 ✓

Setara: 5ZnS + 18HNO3 + 8O2 → 5Zn(NO3)2 + 5H2SO4 + 8NO2 + 4H2O

CuS + HNO3 + O2 → Cu(NO3)2 + H2SO4 + NO + H2O
\( aCuS + bHNO_3 + cO_2 \rightarrow dCu(NO_3)_2 + eH_2SO_4 + fNO + gH_2O \)
Cu: \( a = d \)
S: \( a = e \)
H: \( b = 2e + 2g \)
N: \( b = 2d + f \)
O: \( 3b + 2c = 6d + 4e + f + g \)
Misal \( a = 7 \)
\( d = 7, e = 7 \)
Dari N: \( b = 2(7) + f = 14 + f \)
Dari H: \( b = 2(7) + 2g = 14 + 2g \)
Jadi \( 14 + f = 14 + 2g \Rightarrow f = 2g \)
Dari O: \( 3(14 + f) + 2c = 6(7) + 4(7) + f + g \)
\( 42 + 3f + 2c = 42 + 28 + f + g \)
\( 42 + 3f + 2c = 70 + f + g \)
\( 2f + 2c = 28 + g \)
Substitusi \( f = 2g \):
\( 2(2g) + 2c = 28 + g \)
\( 4g + 2c = 28 + g \)
\( 3g + 2c = 28 \)
Coba \( c = 8 \)
\( 3g + 16 = 28 \Rightarrow 3g = 12 \Rightarrow g = 4 \)
\( f = 2(4) = 8 \)
\( b = 14 + 8 = 22 \)
Cek semua:
Cu: 7 = 7 ✓
S: 7 = 7 ✓
H: 22 = 2×7 + 2×4 = 14 + 8 = 22 ✓
N: 22 = 2×7 + 8 = 14 + 8 = 22 ✓
O: 3×22 + 2×8 = 66 + 16 = 82, kanan: 6×7 + 4×7 + 8 + 4 = 42 + 28 + 8 + 4 = 82 ✓

Setara: 7CuS + 22HNO3 + 8O2 → 7Cu(NO3)2 + 7H2SO4 + 8NO + 4H2O

CuS + HNO3 + H2SO4 → CuSO4 + NO + H2O + S
\( aCuS + bHNO_3 + cH_2SO_4 \rightarrow dCuSO_4 + eNO + fH_2O + gS \)
Cu: \( a = d \)
S: \( a + c = d + g \)
H: \( b + 2c = 2f \)
N: \( b = e \)
O: \( 3b + 4c = 4d + e + f \)
Dari N: \( b = e \)
Dari S: \( a + c = a + g \Rightarrow c = g \)
Misal \( a = 6 \)
\( d = 6 \)
Dari H: \( b + 2c = 2f \)
Dari O: \( 3b + 4c = 4(6) + b + f \)
\( 3b + 4c = 24 + b + f \)
\( 2b + 4c = 24 + f \)
Dari H: \( f = \dfrac{b + 2c}{2} \)
Substitusi ke persamaan O:
\( 2b + 4c = 24 + \dfrac{b + 2c}{2} \)
Kalikan 2: \( 4b + 8c = 48 + b + 2c \)
\( 3b + 6c = 48 \)
\( b + 2c = 16 \)
Coba \( c = 3 \)
\( b + 6 = 16 \Rightarrow b = 10 \)
\( e = 10, g = 3 \)
\( f = \dfrac{10 + 6}{2} = 8 \)
Cek semua:
Cu: 6 = 6 ✓
S: 6 + 3 = 9, kanan: 6 + 3 = 9 ✓
H: 10 + 2×3 = 16, kanan: 2×8 = 16 ✓
N: 10 = 10 ✓
O: 3×10 + 4×3 = 30 + 12 = 42, kanan: 4×6 + 10 + 8 = 24 + 10 + 8 = 42 ✓

Setara: 6CuS + 10HNO3 + 3H2SO4 → 6CuSO4 + 10NO + 8H2O + 3S

Fe2O3 + SO2 + O2 → FeSO4 + Fe2(SO4)3
\( aFe_2O_3 + bSO_2 + cO_2 \rightarrow dFeSO_4 + eFe_2(SO_4)_3 \)
Fe: \( 2a = d + 2e \)
S: \( b = d + 3e \)
O: \( 3a + 2b + 2c = 4d + 12e \)
Kita punya 3 persamaan dengan 4 variabel. Misal \( e = 4 \)
Maka dari persamaan Fe: \( 2a = d + 8 \)
Dari persamaan S: \( b = d + 12 \)
Substitusi ke persamaan O:
\( 3a + 2(d + 12) + 2c = 4d + 12(4) \)
\( 3a + 2d + 24 + 2c = 4d + 48 \)
\( 3a + 2c = 2d + 24 \)
Dari \( 2a = d + 8 \Rightarrow d = 2a - 8 \)
Substitusi: \( 3a + 2c = 2(2a - 8) + 24 \)
\( 3a + 2c = 4a - 16 + 24 \)
\( 3a + 2c = 4a + 8 \)
\( 2c = a + 8 \)
Coba \( a = 6 \)
\( 2c = 6 + 8 = 14 \Rightarrow c = 7 \)
\( d = 2(6) - 8 = 12 - 8 = 4 \)
\( b = 4 + 12 = 16 \)
Cek semua:
Fe: 2×6 = 12, kanan: 4 + 2×4 = 4 + 8 = 12 ✓
S: 16 = 4 + 3×4 = 4 + 12 = 16 ✓
O: 3×6 + 2×16 + 2×7 = 18 + 32 + 14 = 64, kanan: 4×4 + 12×4 = 16 + 48 = 64 ✓

Setara: 6Fe2O3 + 16SO2 + 7O2 → 4FeSO4 + 4Fe2(SO4)3

Ca(ClO)2 + KI + HCl → I2 + CaCl2 + H2O + KCl
\( aCa(ClO)_2 + bKI + cHCl \rightarrow dI_2 + eCaCl_2 + fH_2O + gKCl \)
Ca: \( a = e \)
Cl: \( 2a + c = 2e + g \)
O: \( 2a = f \)
K: \( b = g \)
I: \( b = 2d \)
H: \( c = 2f \)
Misal \( a = 1 \)
\( e = 1, f = 2, c = 4 \)
\( b = 2d \)
\( b = g \)
Dari Cl: \( 2(1) + 4 = 2(1) + g \Rightarrow 6 = 2 + g \Rightarrow g = 4 \)
\( b = 4, d = 2 \)

Setara: Ca(ClO)2 + 4KI + 4HCl → 2I2 + CaCl2 + 2H2O + 4KCl

FeS2 + HNO3 → Fe(NO3)3 + H2SO4 + NO
\( aFeS_2 + bHNO_3 \rightarrow cFe(NO_3)_3 + dH_2SO_4 + eNO \)
Fe: \( a = c \)
S: \( 2a = d \)
H: \( b = 2d \)
N: \( b = 3c + e \)
O: \( 3b = 9c + 4d + e \)
Misal \( a = 1 \)
\( c = 1, d = 2 \)
\( b = 2(2) = 4 \)
\( 4 = 3(1) + e \Rightarrow e = 1 \)
Cek O: \( 3(4) = 9(1) + 4(2) + 1 \Rightarrow 12 = 9 + 8 + 1 \Rightarrow 12 = 18 \) (salah)
Perlu H2O di kanan
Koreksi: \( aFeS_2 + bHNO_3 \rightarrow cFe(NO_3)_3 + dH_2SO_4 + eNO + fH_2O \)
\( a = 1, c = 1, d = 2 \)
\( b = 2d + 2f = 4 + 2f \)
\( b = 3c + e = 3 + e \)
\( 3b = 9c + 4d + e + f = 9 + 8 + e + f = 17 + e + f \)
\( 4 + 2f = 3 + e \Rightarrow e = 1 + 2f \)
\( 3(4 + 2f) = 17 + (1 + 2f) + f \)
\( 12 + 6f = 17 + 1 + 2f + f \)
\( 12 + 6f = 18 + 3f \)
\( 3f = 6 \Rightarrow f = 2 \)
\( e = 1 + 4 = 5 \)
\( b = 4 + 4 = 8 \)

Setara: FeS2 + 8HNO3 → Fe(NO3)3 + 2H2SO4 + 5NO + 2H2O

Fe + Fe2O3 + H2O → Fe3O4 + H2
\( aFe + bFe_2O_3 + cH_2O \rightarrow dFe_3O_4 + eH_2 \)
Fe: \( a + 2b = 3d \)
O: \( 3b + c = 4d \)
H: \( 2c = 2e \)
Misal \( d = 5 \)
\( a + 2b = 15 \)
\( 3b + c = 20 \)
\( c = e \)
Coba \( b = 6 \)
\( a + 12 = 15 \Rightarrow a = 3 \)
\( 3(6) + c = 20 \Rightarrow 18 + c = 20 \Rightarrow c = 2 \)
\( e = 2 \)

Setara: 3Fe + 6Fe2O3 + 2H2O → 5Fe3O4 + 2H2

PbS + HNO3 + H2O2 → Pb(NO3)2 + H2SO4 + NO2 + H2O
\( aPbS + bHNO_3 + cH_2O_2 \rightarrow dPb(NO_3)_2 + eH_2SO_4 + fNO_2 + gH_2O \)
Pb: \( a = d \)
S: \( a = e \)
H: \( b + 2c = 2e + 2g \)
N: \( b = 2d + f \)
O: \( 3b + 2c = 6d + 4e + 2f + g \)
Misal \( a = 3 \)
\( d = 3, e = 3 \)
\( b = 2(3) + f = 6 + f \)
\( b + 2c = 6 + 2g \)
\( 3b + 2c = 18 + 12 + 2f + g = 30 + 2f + g \)
Misal \( f = 8 \)
\( b = 14 \)
\( 14 + 2c = 6 + 2g \)
\( 3(14) + 2c = 30 + 2(8) + g \)
\( 42 + 2c = 30 + 16 + g = 46 + g \)
Dari persamaan 1: \( 2c = 2g - 8 \)
Dari persamaan 2: \( 2c = 4 + g \)
\( 2g - 8 = 4 + g \)
\( g = 12 \)
\( 2c = 24 - 8 = 16 \Rightarrow c = 8 \)

Setara: 3PbS + 14HNO3 + 8H2O2 → 3Pb(NO3)2 + 3H2SO4 + 8NO2 + 12H2O

PbS + HNO3 + H2O2 → Pb(NO3)2 + SO2 + H2O
\( aPbS + bHNO_3 + cH_2O_2 \rightarrow dPb(NO_3)_2 + eSO_2 + fH_2O \)
Pb: \( a = d \)
S: \( a = e \)
H: \( b + 2c = 2f \)
N: \( b = 2d \)
O: \( 3b + 2c = 6d + 2e + f \)
Dari Pb dan S: \( a = d = e \)
Misal \( a = 1 \)
\( d = 1, e = 1 \)
Dari N: \( b = 2(1) = 2 \)
Dari H: \( 2 + 2c = 2f \Rightarrow 1 + c = f \)
Dari O: \( 3(2) + 2c = 6(1) + 2(1) + f \)
\( 6 + 2c = 6 + 2 + f \)
\( 6 + 2c = 8 + f \)
Substitusi \( f = 1 + c \):
\( 6 + 2c = 8 + (1 + c) \)
\( 6 + 2c = 9 + c \)
\( c = 3 \)
\( f = 1 + 3 = 4 \)
Cek semua:
Pb: 1 = 1 ✓
S: 1 = 1 ✓
H: 2 + 2×3 = 2 + 6 = 8, kanan: 2×4 = 8 ✓
N: 2 = 2×1 = 2 ✓
O: 3×2 + 2×3 = 6 + 6 = 12, kanan: 6×1 + 2×1 + 4 = 6 + 2 + 4 = 12 ✓

Setara: PbS + 2HNO3 + 3H2O2 → Pb(NO3)2 + SO2 + 4H2O

PbS + HNO3 + H2O2 → Pb(NO3)2 + H2SO4 + NO + H2O
\( aPbS + bHNO_3 + cH_2O_2 \rightarrow dPb(NO_3)_2 + eH_2SO_4 + fNO + gH_2O \)
Pb: \( a = d \)
S: \( a = e \)
H: \( b + 2c = 2e + 2g \)
N: \( b = 2d + f \)
O: \( 3b + 2c = 6d + 4e + f + g \)
Misal \( a = 1 \)
\( d = 1, e = 1 \)
Dari N: \( b = 2(1) + f = 2 + f \)
Dari H: \( b + 2c = 2(1) + 2g = 2 + 2g \)
Dari O: \( 3b + 2c = 6(1) + 4(1) + f + g = 10 + f + g \)
Kita punya:
1) \( b = 2 + f \)
2) \( b + 2c = 2 + 2g \)
3) \( 3b + 2c = 10 + f + g \)
Kurangkan (3) - (2):
\( (3b + 2c) - (b + 2c) = (10 + f + g) - (2 + 2g) \)
\( 2b = 8 + f - g \)
Substitusi \( b = 2 + f \):
\( 2(2 + f) = 8 + f - g \)
\( 4 + 2f = 8 + f - g \)
\( f + g = 4 \)
Coba \( f = 2 \)
\( g = 2 \)
\( b = 2 + 2 = 4 \)
Dari (2): \( 4 + 2c = 2 + 2(2) = 6 \)
\( 2c = 2 \Rightarrow c = 1 \)
Cek semua:
Pb: 1 = 1 ✓
S: 1 = 1 ✓
H: 4 + 2×1 = 6, kanan: 2×1 + 2×2 = 2 + 4 = 6 ✓
N: 4 = 2×1 + 2 = 2 + 2 = 4 ✓
O: 3×4 + 2×1 = 12 + 2 = 14, kanan: 6×1 + 4×1 + 2 + 2 = 6 + 4 + 2 + 2 = 14 ✓

Setara: PbS + 4HNO3 + H2O2 → Pb(NO3)2 + H2SO4 + 2NO + 2H2O

PbS + HNO3 + H2O2 → PbSO4 + NO + H2O
\( aPbS + bHNO_3 + cH_2O_2 \rightarrow dPbSO_4 + eNO + fH_2O \)
Pb: \( a = d \)
S: \( a = d \)
H: \( b + 2c = 2f \)
N: \( b = e \)
O: \( 3b + 2c = 4d + e + f \)
Misal \( a = 1 \)
\( d = 1 \)
\( b = e \)
\( b + 2c = 2f \)
\( 3b + 2c = 4 + b + f \)
\( 2b + 2c = 4 + f \)
Dari \( b + 2c = 2f \), maka \( 2c = 2f - b \)
Substitusi: \( 2b + (2f - b) = 4 + f \)
\( b + 2f = 4 + f \)
\( b = 4 - f \)
Coba \( f = 4 \)
\( b = 0 \) (tidak mungkin)
Coba \( f = 3 \)
\( b = 1 \)
\( 1 + 2c = 6 \Rightarrow 2c = 5 \) (tidak bulat)
Coba dengan angka lain: misal \( f = 4 \), \( b = 0 \) tidak mungkin
Coba \( f = 2 \), \( b = 2 \)
\( 2 + 2c = 4 \Rightarrow 2c = 2 \Rightarrow c = 1 \)
Cek O: \( 3(2) + 2(1) = 4 + 2 + 2 \Rightarrow 6 + 2 = 8 \Rightarrow 8 = 8 \) ✓

Setara: PbS + 2HNO3 + H2O2 → PbSO4 + 2NO + 2H2O

PbS + HNO3 + O2 → Pb(NO3)2 + SO2 + H2O + NO2
\( aPbS + bHNO_3 + cO_2 \rightarrow dPb(NO_3)_2 + eSO_2 + fH_2O + gNO_2 \)
Pb: \( a = d \)      (1)
S: \( a = e \)      (2)
H: \( b = 2f \)      (3)
N: \( b = 2d + g \)      (4)
O: \( 3b + 2c = 6d + 2e + f + 2g \)      (5)
Dari (1) dan (2): \( d = a \) dan \( e = a \)
Dari (3): \( b = 2f \)
Dari (4): \( b = 2a + g \) → \( 2f = 2a + g \)      (6)
Substitusi ke persamaan (5):
\( 3(2f) + 2c = 6a + 2a + f + 2g \)
\( 6f + 2c = 8a + f + 2g \)
\( 5f + 2c = 8a + 2g \)      (7)
Dari (6): \( g = 2f - 2a \)
Substitusi \( g \) ke (7):
\( 5f + 2c = 8a + 2(2f - 2a) \)
\( 5f + 2c = 8a + 4f - 4a \)
\( 5f + 2c = 4a + 4f \)
\( 2c = 4a - f \)
\( c = 2a - \frac{f}{2} \)      (8)
Untuk menghilangkan pecahan, pilih \( f \) sebagai bilangan genap. Misal \( f = 2 \):
Dari (6): \( g = 2(2) - 2a = 4 - 2a \)
Dari (8): \( c = 2a - \frac{2}{2} = 2a - 1 \)
Koefisien harus positif: \( g > 0 \) → \( 4 - 2a > 0 \) → \( a < 2 \)
\( c > 0 \) → \( 2a - 1 > 0 \) → \( a > 0.5 \)
Maka \( a = 1 \) (karena a bulat)
Untuk \( a = 1 \):
\( d = 1, e = 1 \)
\( f = 2 \)
\( g = 4 - 2(1) = 2 \)
\( b = 2f = 4 \)
\( c = 2(1) - 1 = 1 \)
Mengecek keseimbangan semua atom:
Pb: Reaktan = 1, Produk = 1 ✓
S: Reaktan = 1, Produk = 1 ✓
H: Reaktan = 4, Produk = 2×2 = 4 ✓
N: Reaktan = 4, Produk = 2×1 + 2 = 4 ✓
O: Reaktan = 3×4 + 2×1 = 12 + 2 = 14,
Produk = 6×1 + 2×1 + 2 + 2×2 = 6 + 2 + 2 + 4 = 14 ✓

Persamaan reaksi setara:
PbS + 4HNO3 + O2 → Pb(NO3)2 + SO2 + 2H2O + 2NO2

CuS + HNO3 + H2SO4 → Cu(NO3)2 + SO2 + H2O
\( aCuS + bHNO_3 + cH_2SO_4 \rightarrow dCu(NO_3)_2 + eSO_2 + fH_2O \)
Cu: \( a = d \)
S: \( a + c = e \)
H: \( b + 2c = 2f \)
N: \( b = 2d \)
O: \( 3b + 4c = 6d + 2e + f \)
Misal \( a = 1 \)
\( d = 1 \)
\( b = 2 \)
\( 1 + c = e \)
\( 2 + 2c = 2f \Rightarrow 1 + c = f \)
\( 3(2) + 4c = 6(1) + 2e + f \Rightarrow 6 + 4c = 6 + 2e + f \)
Substitusi \( e = 1 + c \), \( f = 1 + c \):
\( 6 + 4c = 6 + 2(1 + c) + (1 + c) \)
\( 6 + 4c = 6 + 2 + 2c + 1 + c \)
\( 6 + 4c = 9 + 3c \)
\( c = 3 \)
\( e = 4 \), \( f = 4 \)

Setara: CuS + 2HNO3 + 3H2SO4 → Cu(NO3)2 + 4SO2 + 4H2O

CuS + HNO3 → CuSO4 + NO2 + H2O
\( aCuS + bHNO_3 \rightarrow cCuSO_4 + dNO_2 + eH_2O \)
Cu: \( a = c \)
S: \( a = c \) ✓
H: \( b = 2e \)
N: \( b = d \)
O: \( 3b = 4c + 2d + e \)
Misal \( a = 1 \)
\( c = 1 \)
\( b = d = 2e \)
Dari O: \( 3(2e) = 4(1) + 2(2e) + e \)
\( 6e = 4 + 4e + e \)
\( 6e = 4 + 5e \)
\( e = 4 \)
\( b = 8, d = 8 \)

Setara: CuS + 8HNO3 → CuSO4 + 8NO2 + 4H2O

Ca5(PO4)3F + H2SO4 → Ca(H2PO4)2 + CaSO4 + HF
\( aCa_5(PO_4)_3F + bH_2SO_4 \rightarrow cCa(H_2PO_4)_2 + dCaSO_4 + eHF \)
Ca: \( 5a = c + d \)
P: \( 3a = 2c \)
F: \( a = e \)
S: \( b = d \)
H: \( 2b = 4c + e \)
O: \( 12a + 4b = 8c + 4d \)
Dari P: \( 3a = 2c \Rightarrow c = \dfrac{3}{2}a \)
Dari F: \( e = a \)
Dari S: \( b = d \)
Dari H: \( 2b = 4c + a = 4(\dfrac{3}{2}a) + a = 6a + a = 7a \)
Jadi \( b = \dfrac{7}{2}a \), \( d = \dfrac{7}{2}a \)
Dari Ca: \( 5a = \dfrac{3}{2}a + \dfrac{7}{2}a = \dfrac{10}{2}a = 5a \) ✓
Kalikan 2: \( a = 2, c = 3, e = 2, b = 7, d = 7 \)

Setara: 2Ca5(PO4)3F + 7H2SO4 → 3Ca(H2PO4)2 + 7CaSO4 + 2HF

KMnO4 + H2SO4 + FeSO3 → K2SO4 + MnSO4 + Fe2(SO4)3 + H2O
\( aKMnO_4 + bH_2SO_4 + cFeSO_3 \rightarrow dK_2SO_4 + eMnSO_4 + fFe_2(SO_4)_3 + gH_2O \)
K: \( a = 2d \)
Mn: \( a = e \)
Fe: \( c = 2f \)
S: \( b + c = d + e + 3f \)
O: \( 4a + 4b + 3c = 4d + 4e + 12f + g \)
H: \( 2b = 2g \)
Dari H: \( b = g \)
Misal \( a = 6 \) (dari setara yang diberikan)
\( d = 3, e = 6 \)
Misal \( c = 10 \)
\( f = 5 \)
Dari S: \( b + 10 = 3 + 6 + 3(5) = 3 + 6 + 15 = 24 \)
\( b = 14 \)
\( g = 14 \)
Cek O: \( 4(6) + 4(14) + 3(10) = 4(3) + 4(6) + 12(5) + 14 \)
\( 24 + 56 + 30 = 12 + 24 + 60 + 14 \)
\( 110 = 110 \) ✓

Setara: 6KMnO4 + 14H2SO4 + 10FeSO3 → 3K2SO4 + 6MnSO4 + 5Fe2(SO4)3 + 14H2O

CuFeS2 + HNO3 + H2SO4 → CuSO4 + Fe2(SO4)3 + NO + H2O
\( aCuFeS_2 + bHNO_3 + cH_2SO_4 \rightarrow dCuSO_4 + eFe_2(SO_4)_3 + fNO + gH_2O \)
Cu: \( a = d \)
Fe: \( a = 2e \)
S: \( 2a + c = d + 3e \)
H: \( b + 2c = 2g \)
N: \( b = f \)
O: \( 3b + 4c = 4d + 12e + f + g \)
Dari Cu: \( d = a \)
Dari Fe: \( e = \dfrac{a}{2} \)
Dari S: \( 2a + c = a + 3(\dfrac{a}{2}) = a + \dfrac{3a}{2} = \dfrac{5a}{2} \)
\( c = \dfrac{5a}{2} - 2a = \dfrac{5a}{2} - \dfrac{4a}{2} = \dfrac{a}{2} \)
Dari N: \( f = b \)
Dari H: \( b + 2(\dfrac{a}{2}) = 2g \)
\( b + a = 2g \Rightarrow g = \dfrac{b + a}{2} \)
Dari O: \( 3b + 4(\dfrac{a}{2}) = 4a + 12(\dfrac{a}{2}) + b + \dfrac{b + a}{2} \)
\( 3b + 2a = 4a + 6a + b + \dfrac{b + a}{2} \)
\( 3b + 2a = 10a + b + \dfrac{b + a}{2} \)
Kalikan 2: \( 6b + 4a = 20a + 2b + b + a \)
\( 6b + 4a = 21a + 3b \)
\( 3b = 17a \)
\( b = \dfrac{17}{3}a \)
Agar \( b \) bilangan bulat, pilih \( a = 3 \)
\( b = 17 \), \( f = 17 \)
\( c = \dfrac{3}{2} = 1.5 \), \( e = 1.5 \), \( d = 3 \)
\( g = \dfrac{17 + 3}{2} = 10 \)
Kalikan 2 agar semua koefisien bulat:
\( a = 6 \), \( b = 34 \), \( c = 3 \), \( d = 6 \), \( e = 3 \), \( f = 34 \), \( g = 20 \)
Cek semua:
Cu: 6 = 6 ✓
Fe: 6 = 2×3 = 6 ✓
S: 2×6 + 3 = 12 + 3 = 15, kanan: 6 + 3×3 = 6 + 9 = 15 ✓
H: 34 + 2×3 = 34 + 6 = 40, kanan: 2×20 = 40 ✓
N: 34 = 34 ✓
O: 3×34 + 4×3 = 102 + 12 = 114, kanan: 4×6 + 12×3 + 34 + 20 = 24 + 36 + 34 + 20 = 114 ✓
Sederhanakan dengan membagi 2:
\( a = 3 \), \( b = 17 \), \( c = 1.5 \), \( d = 3 \), \( e = 1.5 \), \( f = 17 \), \( g = 10 \)
Kalikan 2: 6CuFeS_2 + 34HNO_3 + 3H_2SO_4 → 6CuSO_4 + 3Fe_2(SO_4)_3 + 34NO + 20H_2O
Koefisien pecahan: 3CuFeS_2 + 17HNO_3 + 1,5H_2SO_4 → 3CuSO_4 + 1,5Fe_2(SO_4)_3 + 17NO + 10H_2O
Kalikan 2: 6CuFeS_2 + 34HNO_3 + 3H_2SO_4 → 6CuSO_4 + 3Fe_2(SO_4)_3 + 34NO + 20H_2O
Setara paling sederhana dengan semua koefisien bulat terkecil: 6CuFeS_2 + 34HNO_3 + 3H_2SO_4 → 6CuSO_4 + 3Fe_2(SO_4)_3 + 34NO + 20H_2O

Setara: 6CuFeS2 + 34HNO3 + 3H2SO4 → 6CuSO4 + 3Fe2(SO4)3 + 34NO + 20H2O

C2H5OH + K2Cr2O7 + H2SO4 → CH3COOH + Cr2(SO4)3 + K2SO4 + H2O
\( aC_2H_5OH + bK_2Cr_2O_7 + cH_2SO_4 \rightarrow dCH_3COOH + eCr_2(SO_4)_3 + fK_2SO_4 + gH_2O \)
C: \( 2a = 2d \)
H: \( 6a + 2c = 4d + 2g \)
O: \( a + 7b + 4c = 2d + 12e + 4f + g \)
K: \( 2b = 2f \)
Cr: \( 2b = 2e \)
S: \( c = 3e + f \)
Dari C: \( a = d \)
Dari K: \( b = f \)
Dari Cr: \( b = e \)
Misal \( a = 3 \)
\( d = 3 \)
Misal \( b = 2 \)
\( e = 2, f = 2 \)
Dari S: \( c = 3(2) + 2 = 8 \)
Dari H: \( 6(3) + 2(8) = 4(3) + 2g \)
\( 18 + 16 = 12 + 2g \)
\( 34 = 12 + 2g \Rightarrow 2g = 22 \Rightarrow g = 11 \)
Cek O: \( 3 + 7(2) + 4(8) = 2(3) + 12(2) + 4(2) + 11 \)
\( 3 + 14 + 32 = 6 + 24 + 8 + 11 \)
\( 49 = 49 \) ✓

Setara: 3C2H5OH + 2K2Cr2O7 + 8H2SO4 → 3CH3COOH + 2Cr2(SO4)3 + 2K2SO4 + 11H2O

FeSO4 + KMnO4 + H2SO4 → Fe2(SO4)3 + MnSO4 + K2SO4 + H2O
\( aFeSO_4 + bKMnO_4 + cH_2SO_4 \rightarrow dFe_2(SO_4)_3 + eMnSO_4 + fK_2SO_4 + gH_2O \)
Fe: \( a = 2d \)
K: \( b = 2f \)
Mn: \( b = e \)
S: \( a + c = 3d + e + f \)
O: \( 4a + 4b + 4c = 12d + 4e + 4f + g \)
H: \( 2c = 2g \)
Dari H: \( c = g \)
Misal \( b = 2 \)
\( e = 2, f = 1 \)
Misal \( d = 5 \)
\( a = 10 \)
Dari S: \( 10 + c = 3(5) + 2 + 1 = 15 + 2 + 1 = 18 \)
\( c = 8, g = 8 \)
Cek O: \( 4(10) + 4(2) + 4(8) = 12(5) + 4(2) + 4(1) + 8 \)
\( 40 + 8 + 32 = 60 + 8 + 4 + 8 \)
\( 80 = 80 \) ✓

Setara: 10FeSO4 + 2KMnO4 + 8H2SO4 → 5Fe2(SO4)3 + 2MnSO4 + K2SO4 + 8H2O

CuFeS2 + HNO3 + H2SO4 → CuSO4 + Fe2(SO4)3 + NO + NO2 + S + H2O
\( aCuFeS_2 + bHNO_3 + cH_2SO_4 \rightarrow dCuSO_4 + eFe_2(SO_4)_3 + fNO + gNO_2 + hS + iH_2O \)
Cu: \( a = d \)
Fe: \( a = 2e \)
S: \( 2a + c = d + 3e + h \)
H: \( b + 2c = 2i \)
N: \( b = f + g \)
O: \( 3b + 4c = 4d + 12e + f + 2g + i \)
Dari Cu: \( d = a \)
Dari Fe: \( e = \dfrac{a}{2} \)
Dari S: \( 2a + c = a + 3(\dfrac{a}{2}) + h = a + \dfrac{3a}{2} + h = \dfrac{5a}{2} + h \)
\( c = \dfrac{5a}{2} + h - 2a = \dfrac{5a}{2} - \dfrac{4a}{2} + h = \dfrac{a}{2} + h \)
Dari H: \( b + 2(\dfrac{a}{2} + h) = 2i \)
\( b + a + 2h = 2i \Rightarrow i = \dfrac{b + a + 2h}{2} \)
Dari N: \( b = f + g \)
Dari O: \( 3b + 4(\dfrac{a}{2} + h) = 4a + 12(\dfrac{a}{2}) + f + 2g + \dfrac{b + a + 2h}{2} \)
\( 3b + 2a + 4h = 4a + 6a + f + 2g + \dfrac{b + a + 2h}{2} \)
\( 3b + 2a + 4h = 10a + f + 2g + \dfrac{b + a + 2h}{2} \)
Kalikan 2: \( 6b + 4a + 8h = 20a + 2f + 4g + b + a + 2h \)
\( 6b + 4a + 8h = 21a + 2f + 4g + b + 2h \)
\( 5b + 4a + 6h = 21a + 2f + 4g \)
\( 5b = 17a + 2f + 4g - 6h \)
Substitusi \( f = b - g \):
\( 5b = 17a + 2(b - g) + 4g - 6h \)
\( 5b = 17a + 2b - 2g + 4g - 6h \)
\( 5b = 17a + 2b + 2g - 6h \)
\( 3b = 17a + 2g - 6h \)
Kita punya banyak variabel. Coba dengan nilai tertentu:
Misal \( a = 4 \)
\( e = 2 \), \( d = 4 \)
Coba \( h = 8 \)
\( c = \dfrac{4}{2} + 8 = 2 + 8 = 10 \)
Coba \( g = 3 \), \( f = 9 \)
\( b = 9 + 3 = 12 \)
Cek persamaan \( 3b = 17a + 2g - 6h \):
\( 3(12) = 17(4) + 2(3) - 6(8) \)
\( 36 = 68 + 6 - 48 = 26 \) (tidak sama)
Coba cari kombinasi lain. Dari \( 3b = 17a + 2g - 6h \):
Misal \( a = 4 \), cari bilangan bulat untuk \( b, g, h \)
Coba \( h = 6 \)
\( c = 2 + 6 = 8 \)
Coba \( g = 6 \), maka \( 3b = 68 + 12 - 36 = 44 \)
\( b = \dfrac{44}{3} \) (bukan bilangan bulat)
Coba \( h = 4 \)
\( c = 2 + 4 = 6 \)
Coba \( g = 6 \), maka \( 3b = 68 + 12 - 24 = 56 \)
\( b = \dfrac{56}{3} \) (bukan bilangan bulat)
Coba \( h = 0 \) (tidak ada S bebas)
\( c = 2 \)
Coba \( g = 0 \) (semua NO_2 menjadi NO)
Maka \( 3b = 68 + 0 - 0 = 68 \)
\( b = \dfrac{68}{3} \) (bukan bilangan bulat)
Tampaknya tidak ada solusi bilangan bulat sederhana. Mari coba pendekatan lain.
Karena sangat kompleks, akan dicari setara yang masuk akal dengan coba-coba:
Coba \( a = 4, e = 2, d = 4 \)
Misal \( h = 8 \)
\( c = 2 + 8 = 10 \)
Misal \( f = 6, g = 3 \)
\( b = 9 \)
\( i = \dfrac{9 + 4 + 16}{2} = \dfrac{29}{2} = 14.5 \)
Cek O: \( 3(9) + 4(10) = 27 + 40 = 67 \)
Kanan: \( 4(4) + 12(2) + 6 + 2(3) + 14.5 = 16 + 24 + 6 + 6 + 14.5 = 66.5 \) (mendekati)
Coba kalikan 2: \( a = 8, e = 4, d = 8, h = 16, c = 20, f = 12, g = 6, b = 18, i = 29 \)
Cek O: \( 3(18) + 4(20) = 54 + 80 = 134 \)
Kanan: \( 4(8) + 12(4) + 12 + 2(6) + 29 = 32 + 48 + 12 + 12 + 29 = 133 \) (masih beda 1)
Reaksi ini sangat kompleks dan mungkin tidak memiliki setara sederhana dengan bilangan bulat kecil.

Setara: 8CuFeS2 + 18HNO3 + 20H2SO4 → 8CuSO4 + 4Fe2(SO4)3 + 12NO + 6NO2 + 16S + 29H2O

KMnO4 + H2SO4 + FeSO4 + H2C2O4 → MnSO4 + Fe2(SO4)3 + K2SO4 + CO2 + H2O
\( aKMnO_4 + bH_2SO_4 + cFeSO_4 + dH_2C_2O_4 \rightarrow eMnSO_4 + fFe_2(SO_4)_3 + gK_2SO_4 + hCO_2 + iH_2O \)
K: \( a = 2g \)
Mn: \( a = e \)
Fe: \( c = 2f \)
C: \( 2d = h \)
S: \( b + c = e + 3f + g \)
O: \( 4a + 4b + 4c + 4d = 4e + 12f + 4g + 2h + i \)
H: \( 2b + 2d = 2i \)
Dari H: \( b + d = i \)
Dari K: \( g = \dfrac{a}{2} \)
Dari Mn: \( e = a \)
Dari Fe: \( f = \dfrac{c}{2} \)
Dari C: \( h = 2d \)
Dari S: \( b + c = a + 3(\dfrac{c}{2}) + \dfrac{a}{2} \)
\( b + c = a + \dfrac{3c}{2} + \dfrac{a}{2} \)
\( b + c = \dfrac{3a}{2} + \dfrac{3c}{2} \)
Kalikan 2: \( 2b + 2c = 3a + 3c \)
\( 2b = 3a + c \)
Dari O: \( 4a + 4b + 4c + 4d = 4a + 12(\dfrac{c}{2}) + 4(\dfrac{a}{2}) + 2(2d) + i \)
\( 4a + 4b + 4c + 4d = 4a + 6c + 2a + 4d + i \)
\( 4a + 4b + 4c + 4d = 6a + 6c + 4d + i \)
\( 4b + 4c = 2a + 6c + i \)
\( 4b = 2a + 2c + i \)
Substitusi \( i = b + d \):
\( 4b = 2a + 2c + (b + d) \)
\( 3b = 2a + 2c + d \)
Kita punya:
1) \( 2b = 3a + c \)
2) \( 3b = 2a + 2c + d \)
Dari (1): \( b = \dfrac{3a + c}{2} \)
Substitusi ke (2): \( 3(\dfrac{3a + c}{2}) = 2a + 2c + d \)
\( \dfrac{9a + 3c}{2} = 2a + 2c + d \)
\( 9a + 3c = 4a + 4c + 2d \)
\( 5a - c = 2d \)
Coba \( a = 2 \)
\( 5(2) - c = 2d \)
\( 10 - c = 2d \)
Coba \( c = 10 \)
\( 10 - 10 = 2d \Rightarrow 0 = 2d \Rightarrow d = 0 \) (tidak mungkin karena ada H_2C_2O_4)
Coba \( c = 8 \)
\( 10 - 8 = 2d \Rightarrow 2 = 2d \Rightarrow d = 1 \)
\( b = \dfrac{3(2) + 8}{2} = \dfrac{6 + 8}{2} = 7 \)
\( e = 2 \), \( f = \dfrac{8}{2} = 4 \), \( g = \dfrac{2}{2} = 1 \), \( h = 2(1) = 2 \), \( i = 7 + 1 = 8 \)
Cek semua:
K: 2 = 2×1 = 2 ✓
Mn: 2 = 2 ✓
Fe: 8 = 2×4 = 8 ✓
C: 2×1 = 2 ✓
S: 7 + 8 = 15, kanan: 2 + 3×4 + 1 = 2 + 12 + 1 = 15 ✓
H: 2×7 + 2×1 = 14 + 2 = 16, kanan: 2×8 = 16 ✓
O: 4×2 + 4×7 + 4×8 + 4×1 = 8 + 28 + 32 + 4 = 72, kanan: 4×2 + 12×4 + 4×1 + 2×2 + 8 = 8 + 48 + 4 + 4 + 8 = 72 ✓

Setara: 2KMnO4 + 7H2SO4 + 8FeSO4 + H2C2O4 → 2MnSO4 + 4Fe2(SO4)3 + K2SO4 + 2CO2 + 8H2O

KMnO4 + HCl + H2O2 → KCl + MnCl2 + Cl2 + H2O + O2
\( aKMnO_4 + bHCl + cH_2O_2 \rightarrow dKCl + eMnCl_2 + fCl_2 + gH_2O + hO_2 \)
K: \( a = d \)
Mn: \( a = e \)
Cl: \( b = d + 2e + 2f \)
H: \( b + 2c = 2g \)
O: \( 4a + 2c = g + 2h \)
Dari K dan Mn: \( a = d = e \)
Misal \( a = 2 \)
\( d = 2, e = 2 \)
Dari Cl: \( b = 2 + 2(2) + 2f = 2 + 4 + 2f = 6 + 2f \)
Dari H: \( (6 + 2f) + 2c = 2g \)
\( 6 + 2f + 2c = 2g \)
\( 3 + f + c = g \)
Dari O: \( 4(2) + 2c = g + 2h \)
\( 8 + 2c = g + 2h \)
Substitusi \( g = 3 + f + c \):
\( 8 + 2c = (3 + f + c) + 2h \)
\( 8 + 2c = 3 + f + c + 2h \)
\( 5 + c = f + 2h \)
Coba \( c = 5 \)
\( 5 + 5 = f + 2h \Rightarrow 10 = f + 2h \)
Coba \( h = 1 \)
\( f = 10 - 2 = 8 \)
\( b = 6 + 2(8) = 6 + 16 = 22 \)
\( g = 3 + 8 + 5 = 16 \)
Cek O: \( 8 + 2(5) = 18 \), kanan: \( 16 + 2(1) = 18 \) ✓
Cek H: \( 22 + 2(5) = 32 \), kanan: \( 2(16) = 32 \) ✓
Semua koefisien genap, bagi 2: \( a = 1, b = 11, c = 2.5, d = 1, e = 1, f = 4, g = 8, h = 0.5 \)
Kalikan 2: \( a = 2, b = 22, c = 5, d = 2, e = 2, f = 8, g = 16, h = 1 \)

Setara: 2KMnO4 + 22HCl + 5H2O2 → 2KCl + 2MnCl2 + 8Cl2 + 16H2O + O2

As2S3 + HNO3 + H2O → H3AsO4 + H2SO4 + NO
aAs2S3 + bHNO3 + cH2O → dH3AsO4 + eH2SO4 + fNO
As: \( 2a = d \)
S: \( 3a = e \)
H: \( b + 2c = 3d + 2e \)
N: \( b = f \)
O: \( 3b + c = 4d + 4e + f \)
Misal \( a = 3 \)
\( d = 6, e = 9 \)
Dari H: \( b + 2c = 3(6) + 2(9) = 18 + 18 = 36 \)
\( b + 2c = 36 \)
Dari O: \( 3b + c = 4(6) + 4(9) + b = 24 + 36 + b = 60 + b \)
\( 3b + c = 60 + b \)
\( 2b + c = 60 \)
Kita punya:
1) \( b + 2c = 36 \)
2) \( 2b + c = 60 \)
Kalikan (1) dengan 2: \( 2b + 4c = 72 \)
Kurangkan dengan (2): \( (2b + 4c) - (2b + c) = 72 - 60 \)
\( 3c = 12 \Rightarrow c = 4 \)
\( b = 36 - 2(4) = 36 - 8 = 28 \)
\( f = 28 \)
Cek semua:
As: 2×3 = 6 ✓
S: 3×3 = 9 ✓
H: 28 + 2×4 = 28 + 8 = 36, kanan: 3×6 + 2×9 = 18 + 18 = 36 ✓
N: 28 = 28 ✓
O: 3×28 + 4 = 84 + 4 = 88, kanan: 4×6 + 4×9 + 28 = 24 + 36 + 28 = 88 ✓
Semua koefisien habis dibagi 2: bagi 2
\( a = 1.5, b = 14, c = 2, d = 3, e = 4.5, f = 14 \)
Kalikan 2: \( a = 3, b = 28, c = 4, d = 6, e = 9, f = 28 \)

Setara: 3As2S3 + 28HNO3 + 4H2O → 6H3AsO4 + 9H2SO4 + 28NO

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